Ontology highlight
ABSTRACT:
SUBMITTER: Wu P
PROVIDER: S-EPMC6761133 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Wu Pengyan P Li Yang Y Zheng Jia-Jia JJ Hosono Nobuhiko N Otake Ken-Ichi KI Wang Jian J Liu Yanhong Y Xia Lingling L Jiang Min M Sakaki Shigeyoshi S Kitagawa Susumu S
Nature communications 20190925 1
Direct structural information of confined CO<sub>2</sub> in a micropore is important for elucidating its specific binding or activation mechanism. However, weak gas-binding ability and/or poor sample crystallinity after guest exchange hindered the development of efficient materials for CO<sub>2</sub> incorporation, activation and conversion. Here, we present a dynamic porous coordination polymer (PCP) material with local flexibility, in which the propeller-like ligands rotate to permit CO<sub>2< ...[more]