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Porous Multicomponent Mn-Sn-Co Oxide Microspheres as Anodes for High-Performance Lithium-Ion Batteries.


ABSTRACT: Porous multicomponent Mn-Sn-Co oxide microspheres (MnSnO3-MC400 and MnSnO3-MC500) have been fabricated using CoSn(OH)6 nanocubes as templates via controlling pyrolysis of a CoSn(OH)6/Mn0.5Co0.5CO3 precursor at different temperatures in N2. During the pyrolysis process of CoSn(OH)6/Mn0.5Co0.5CO3 from 400 to 500 °C, the part of (Co,Mn)(Co,Mn)2O4 converts into MnCo2O4 accompanied with structural transformation. The MnSnO3-MC400 and MnSnO3-MC500 microspheres as secondary nanomaterials consist of MnSnO3, MnCo2O4, and (Co,Mn)(Co,Mn)2O4. Benefiting from the advantages of multicomponent synergy and porous secondary nanomaterials, the MnSnO3-MC400 and MnSnO3-MC500 microspheres as anodes exhibit the specific capacities of 1030 and 750 mA h g-1 until 1000 cycles at 1 A g-1 without an obvious capacity decay, respectively.

SUBMITTER: Yang H 

PROVIDER: S-EPMC6777295 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Porous Multicomponent Mn-Sn-Co Oxide Microspheres as Anodes for High-Performance Lithium-Ion Batteries.

Yang Hongxun H   Wu Bin B   Liu Yongmin Y   Wang Zhenkang Z   Xu Minghang M   Yang Tongyi T   Chen Yingying Y   Wang Changhua C   Lin Shengling S  

ACS omega 20190916 14


Porous multicomponent Mn-Sn-Co oxide microspheres (MnSnO<sub>3</sub>-MC400 and MnSnO<sub>3</sub>-MC500) have been fabricated using CoSn(OH)<sub>6</sub> nanocubes as templates via controlling pyrolysis of a CoSn(OH)<sub>6</sub>/Mn<sub>0.5</sub>Co<sub>0.5</sub>CO<sub>3</sub> precursor at different temperatures in N<sub>2</sub>. During the pyrolysis process of CoSn(OH)<sub>6</sub>/Mn<sub>0.5</sub>Co<sub>0.5</sub>CO<sub>3</sub> from 400 to 500 °C, the part of (Co,Mn)(Co,Mn)<sub>2</sub>O<sub>4</sub>  ...[more]

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