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ABSTRACT:
SUBMITTER: Konrath R
PROVIDER: S-EPMC6837175 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Chemical science 20190723 35
The selective catalytic hydrogenation of nitriles represents an important but challenging transformation for many homogeneous and heterogeneous catalysts. Herein, we report the efficient and modular solid-phase synthesis of immobilized Triphos-type ligands in very high yields, involving only minimal work-up procedures. The corresponding supported ruthenium-Triphos catalysts are tested in the hydrogenation of various nitriles. Under mild conditions and without the requirement of additives, the tu ...[more]