Ontology highlight
ABSTRACT:
SUBMITTER: Makarov AS
PROVIDER: S-EPMC6839507 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Chemical science 20190726 37
An intramolecular rhodium-catalyzed reaction of 1-tosyl-1,2,3-triazoles with furans has been explored. The tosylimino functionality was found to play a significant chemical role participating in the subsequent domino-transformations of a key reaction intermediate. One of the reaction pathways leads to valuable 2-formyl- and 2-acetylpyridine building blocks, which could be obtained in <i>one-pot</i> starting from easily accessible (furan-2-ylmethyl)propargyl amines. An original method for the syn ...[more]