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Predicting sedimentary bedrock subsurface weathering fronts and weathering rates.

ABSTRACT: Although bedrock weathering strongly influences water quality and global carbon and nitrogen budgets, the weathering depths and rates within subsurface are not well understood nor predictable. Determination of both porewater chemistry and subsurface water flow are needed in order to develop more complete understanding and obtain weathering rates. In a long-term field study, we applied a multiphase approach along a mountainous watershed hillslope transect underlain by marine shale. Here we report three findings. First, the deepest extent of the water table determines the weathering front, and the range of annually water table oscillations determines the thickness of the weathering zone. Below the lowest water table, permanently water-saturated bedrock remains reducing, preventing deeper pyrite oxidation. Secondly, carbonate minerals and potentially rock organic matter share the same weathering front depth with pyrite, contrary to models where weathering fronts are stratified. Thirdly, the measurements-based weathering rates from subsurface shale are high, amounting to base cation exports of about 70 kmol_c ha^-1 y^-1, yet consistent with weathering of marine shale. Finally, by integrating geochemical and hydrological data we present a new conceptual model that can be applied in other settings to predict weathering and water quality responses to climate change.

SUBMITTER: Wan J

PROVIDER: S-EPMC6868182 | biostudies-literature | 2019 Nov

REPOSITORIES: biostudies-literature

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Predicting sedimentary bedrock subsurface weathering fronts and weathering rates.

Wan Jiamin J Tokunaga Tetsu K TK Williams Kenneth H KH Dong Wenming W Brown Wendy W Henderson Amanda N AN Newman Alexander W AW Hubbard Susan S SS

Scientific reports 20191120 1

Although bedrock weathering strongly influences water quality and global carbon and nitrogen budgets, the weathering depths and rates within subsurface are not well understood nor predictable. Determination of both porewater chemistry and subsurface water flow are needed in order to develop more complete understanding and obtain weathering rates. In a long-term field study, we applied a multiphase approach along a mountainous watershed hillslope transect underlain by marine shale. Here we report ...[more]

PMID: 31748585

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Project description:The immovable nature of built heritage means that it is particularly vulnerable during times of armed conflict. Although impacts from small arms and shrapnel leave relatively inconspicuous impact scars, they elevate the risk of future stone deterioration. This study investigates the subsurface damage caused by bullet impacts, which is not apparent from surface inspection, in order to better understand the geometry and mechanics of this form of conflict damage to heritage. Controlled firearm experiments were conducted to simulate conflict damage to sandstone and limestone buildings. The bullet impacts created conical fractures or zones of increased fracture intensity below the impact, radial fractures, and spallation, in addition to a crater. Dynamic fracture distinguishes the formation of these features from quasi static cone crack experiments, while the lack of a shockwave differentiates these bullet impacts from hypervelocity experiments. Damage was created by momentum transfer from the bullet, so that differences in target properties had large effects on the nature of the damage. The crater in the limestone target was almost an order of magnitude deeper than the sandstone crater, and large open fractures formed in the limestone below the crater floor, compared with zones of increased fracture intensity in the sandstone target. Microstructural analysis of subsurface damage showed that fracture intensity decreased with increasing distance from the impact centre, suggesting that regions proximal to the impact are at increased risk of future deterioration. Conical subsurface fractures dipping away from the impact beneath multiple impact craters could link up, creating a continuous fracture network. By providing pathways for moisture and other weathering agents, fractures enlarge the region at increased risk of deterioration. Their lack of surface expression makes understanding their formation a vital part of future surveying and post conflict assessments.

Dataset Information

Predicting sedimentary bedrock subsurface weathering fronts and weathering rates.

Publications

Predicting sedimentary bedrock subsurface weathering fronts and weathering rates.

Similar Datasets

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