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Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters.

ABSTRACT: Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (CPP), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are given. Pseudo-first order rate constants are determined for CPP at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation.

SUBMITTER: Terekhov VE

PROVIDER: S-EPMC6909154 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Hydrolysis data for bis(4-cyanophenyl) phenyl phosphate including rate constants and activation parameters.

Terekhov V E VE Aleshkevich V V VV Afanaseva E S ES Nechausov S S SS Babkin A V AV Bulgakov B A BA Kepman A V AV Avdeev V V VV

Data in brief 20191122

Hydrolysis data for Bis(4-cyanophenyl) phenyl phosphate (<b>CPP</b>), introduced as a reactive diluent for phthalonitrile monomers, under pH 4, 7 and 10 are presented. Conversion/time plots collected by HPLC analysis, typical chromatograms and NMR spectra of the substrate and the reaction products are given. Pseudo-first order rate constants are determined for <b>CPP</b> at 25, 50 and 80 °C. Activation parameters were calculated from Arrhenius equation. ...[more]

PMID: 31871997

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