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Regioselective Oxidative Arylation of Fluorophenols.


ABSTRACT: A metal free and highly regioselective oxidative arylation reaction of fluorophenols is described. The relative position of the fluoride leaving group (i.e., ortho or para) controls the 1,2 or 1,4 nature of the arylated quinone product, lending versatility and generality to this oxidative, defluorinative, arylation concept.

SUBMITTER: Yu C 

PROVIDER: S-EPMC6916641 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Regioselective Oxidative Arylation of Fluorophenols.

Yu Congjun C   Patureau Frederic W FW  

Angewandte Chemie (International ed. in English) 20191031 51


A metal free and highly regioselective oxidative arylation reaction of fluorophenols is described. The relative position of the fluoride leaving group (i.e., ortho or para) controls the 1,2 or 1,4 nature of the arylated quinone product, lending versatility and generality to this oxidative, defluorinative, arylation concept. ...[more]

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