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Bis{4-[(2-hy-droxy-5-meth-oxy-3-nitro-benzyl-idene)amino]-phen-yl} ether.


ABSTRACT: The mol-ecule of the title compound, C28H22N4O9, exhibits crystallographically imposed twofold rotational symmetry, with a dihedral angle of 66.0?(2)° between the planes of the two central benzene rings bounded to the central oxygen atom. The dihedral angle between the planes of the central benzene ring and the terminal phenol ring is 4.9?(2)°. Each half of the mol-ecule exhibits an imine E configuration. An intra-molecular O-H?N hydrogen bond is present. In the crystal, the mol-ecules are linked into layers parallel to the ab plane via C-H?O hydrogen bonds. The crystal studied was refined as a two-component pseudomerohedral twin.

SUBMITTER: Arafath MA 

PROVIDER: S-EPMC6944087 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Bis{4-[(2-hy-droxy-5-meth-oxy-3-nitro-benzyl-idene)amino]-phen-yl} ether.

Arafath Md Azharul MA   Kwong Huey Chong HC   Adam Farook F   Mohiuddin Md M   Sarker Md Sohug MS   Salim Mohammad M   Alam Md Mahbubul MM  

Acta crystallographica. Section E, Crystallographic communications 20200101 Pt 1


The mol-ecule of the title compound, C<sub>28</sub>H<sub>22</sub>N<sub>4</sub>O<sub>9</sub>, exhibits crystallographically imposed twofold rotational symmetry, with a dihedral angle of 66.0 (2)° between the planes of the two central benzene rings bounded to the central oxygen atom. The dihedral angle between the planes of the central benzene ring and the terminal phenol ring is 4.9 (2)°. Each half of the mol-ecule exhibits an imine <i>E</i> configuration. An intra-molecular O-H⋯N hydrogen bond i  ...[more]

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