Ontology highlight
ABSTRACT:
SUBMITTER: Neuhaus WC
PROVIDER: S-EPMC7043397 | biostudies-literature | 2019 Dec
REPOSITORIES: biostudies-literature
ACS catalysis 20191023 12
The oxidative homocoupling of <i>para</i>-alkenyl phenols and subsequent trapping of the resulting quinone methide with a variety of oxygen and nitrogen nucleophiles was achieved. Both β-β and β-O coupling isomers can be synthesized via either C-C coupling and two nucleophilic additions of one water molecule (β-β isomer) or C-O coupling followed by one nucleophilic addition of a water molecule (β-O isomer), respectively. Selectivity between these outcomes was achieved by leveraging understanding ...[more]