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A Double-Band Emitter with Ultranarrow-Band Blue and Narrow-Band Green Luminescence.

ABSTRACT: Understanding the origin and mechanisms of luminescence is a crucial point when it comes to the development of new phosphors with targeted luminescence properties. Herein, a new phosphor belonging to the substance class of alkali metal lithosilicates with the generalized sum formula Cs_4-x-y-z Rb_x Na_y Li_z [Li₃ SiO₄ ]₄ :Eu²⁺ is reported. Single crystals of the cyan-emitting UCr₄ C₄ -type phosphor show a peculiar double-band luminescence with one ultranarrow emission band at 473 nm and a narrow emission band at 531 nm under excitation with UV light (λ_exc =408 nm). Regarding occupation of the channels by the light metal ions, investigations of single-crystal XRD data led to the assumption that domain formation with distinct lithium- and sodium-filled channels occurs. Depending on which of these channels hosts the activator ion Eu²⁺ , a green or blue emission results. The herein-presented results shed new light on the luminescence process in the well-studied UCr₄ C₄ -type alkali metal lithosilicate phosphors.

SUBMITTER: Ruegenberg F

PROVIDER: S-EPMC7065093 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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A Double-Band Emitter with Ultranarrow-Band Blue and Narrow-Band Green Luminescence.

Ruegenberg Freia F Seibald Markus M Baumann Dominik D Peschke Simon S Schmid Philipp C PC Huppertz Hubert H

Chemistry (Weinheim an der Bergstrasse, Germany) 20200121 10

Understanding the origin and mechanisms of luminescence is a crucial point when it comes to the development of new phosphors with targeted luminescence properties. Herein, a new phosphor belonging to the substance class of alkali metal lithosilicates with the generalized sum formula Cs4-x-y-z Rbx Nay Liz [Li3 SiO4 ]4 :Eu2+ is reported. Single crystals of the cyan-emitting UCr4 C4 -type p ...[more]

PMID: 31711269

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Project description:Psoriasis is a common chronic inflammatory and hyperproliferative immune-mediated skin disorder. Narrow-band UVB (NB-UVB) phototherapy is a convenient first-line treatment of psoriasis, though the mechanisms underlying its efficacy have not been completely elucidated. In order to improve our understanding of NB-UVB phototherapy, gene expression profiling was used to characterize gene expression in lesional epidermis from psoriasis patients undergoing NB-UVB phototherapy. Increased expression of melanogenesis pathway genes was observed to be the earliest response. At the end of treatment, genes involved in diverse biological processes were affected, such as pigmentation, cell adhesion, ectodermal development and metabolism. The relationship between gene expression and treatment outcome was further studied using Partial Least Squares Discriminant Analysis (PLS-DA). Gene ontology analysis showed that genes responding to phototherapy and highly correlated to treatment outcome were involved in oxidation reduction, growth and mitochondria organization. In particular SPATA18, a key regulator of mitochondria quality, was found to be significantly downregulated in psoriasis, and its upregulation following phototherapy was required for optimal clinical improvement. Our data suggest that oxidation reduction is a critical event for the resolution of psoriatic plaques. Twelve patients diagnosed with plaque type psoriasis were recruited to the study. NB-UVB irradiation was administered to the whole body two to three times a week. Treatment comprising approximately 24 sessions was given during two to three months. A total of six 4 mm diameter punch biopsies were taken from lesions on each psoriasis patient: two prior to UV treatment (pre-UV), two at the middle stage of UV treatment (after about one month of treatment, mid-UV) and two before the last treatment session (post-UV). Twelve healthy age-, sex- and skin type-matched volunteers were also recruited and two punch biopsies were taken from the buttocks. RNA was extracted from Laser capture microdissected epidermis.

Dataset Information

A Double-Band Emitter with Ultranarrow-Band Blue and Narrow-Band Green Luminescence.

Publications

A Double-Band Emitter with Ultranarrow-Band Blue and Narrow-Band Green Luminescence.

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