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Relay Cross Metathesis for the Iterative Construction of Terpenoids and Synthesis of a Diterpene-Benzoate Macrolide of Biogenetic Relevance to the Bromophycolides.
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ABSTRACT:
SUBMITTER: Bahou KA
PROVIDER: S-EPMC7171603 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
Publications
Relay Cross Metathesis for the Iterative Construction of Terpenoids and Synthesis of a Diterpene-Benzoate Macrolide of Biogenetic Relevance to the Bromophycolides.
Organic letters 20200331 8
We report a relay cross metathesis (ReXM) reaction for the construction of terpenoids in an iterative protocol. The protocol features the cross metathesis of a relay-actuated Δ<sup>6,7</sup>-functionalized C<sub>10</sub>-monoterpenoid alcohol with C<sub>10</sub>-monoterpenoid citral to form a C<sub>15</sub>-sesquiterpene. Subsequent functional group manipulation allows for the method to be repeated in an iterative fashion. The method is used for the synthesis of a diterpene-benzoate macrolide of ...[more]