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An Efficient Metal-Free Oxidative Esterification and Amination of Benzyl C-H Bond.


ABSTRACT: An esterification and amination of benzylic C-H bonds was developed by using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under metal- and iodide-free conditions. Both carboxylic acids and amines could be used as ideal coupling partners for the oxidative coupling reactions with various diarylmethanes. A close to equal amount of coupling reagents was enough to afford the product in good to high yields.

SUBMITTER: Liu S 

PROVIDER: S-EPMC7180972 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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An Efficient Metal-Free Oxidative Esterification and Amination of Benzyl C-H Bond.

Liu Saiwen S   Chen Ru R   He Guowen G   Zhang Jin J  

Molecules (Basel, Switzerland) 20200327 7


An esterification and amination of benzylic C-H bonds was developed by using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) under metal- and iodide-free conditions. Both carboxylic acids and amines could be used as ideal coupling partners for the oxidative coupling reactions with various diarylmethanes. A close to equal amount of coupling reagents was enough to afford the product in good to high yields. ...[more]

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