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Influence of Nanoparticles on Thermal and Electrical Conductivity of Composites.

ABSTRACT: This review analyzes thermal and electrically conductive properties of composites and how they can be influenced by the addition of special nanoparticles. Composite functional characteristics-such as thermal and electrical conductivity, phase changes, dimensional stability, magnetization, and modulus increase-are tuned by selecting suitable nanoparticle filler material. The conductivity of composites can be related to the formation of conductive pathways as nanofiller materials form connections in the bulk of a composite matrix. With increasing use of nanomaterial containing composites and relatively little understanding of the toxicological effects thereof, adequate disposal and recyclability have become an increasing environmental concern.

SUBMITTER: Coetzee D

PROVIDER: S-EPMC7240543 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature

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Influence of Nanoparticles on Thermal and Electrical Conductivity of Composites.

Coetzee Divan D Venkataraman Mohanapriya M Militky Jiri J Petru Michal M

Polymers 20200327 4

This review analyzes thermal and electrically conductive properties of composites and how they can be influenced by the addition of special nanoparticles. Composite functional characteristics-such as thermal and electrical conductivity, phase changes, dimensional stability, magnetization, and modulus increase-are tuned by selecting suitable nanoparticle filler material. The conductivity of composites can be related to the formation of conductive pathways as nanofiller materials form connections ...[more]

PMID: 32230802

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Project description:This paper presents the synthesis and physicochemical characterization of a new hybrid composite. Its main goals are evaluating the structure and studying the thermal and mechanical properties of the crosslinked polymeric materials based on varying chemical properties of the compounds. As an organic crosslinking monomer, bisphenol A glycerolate diacrylate (BPA.GDA) was used. Trimethoxyvinylsilane (TMVS) and N-vinyl-2-pyrrolidone (NVP) were used as comonomers and active diluents. The inorganic fraction was the silica in the form of nanoparticles (NANOSiO2). The hybrid composites were obtained by the bulk polymerization method using the UV initiator Irqacure 651 with a constant weight ratio of the tetrafunctional monomer BPA.GDA to TMVS or NVP (7:3 wt.%) and different wt.% of silica nanoparticles (0, 1, 3%). The proper course of polymerization was confirmed by the ATR/FTIR spectroscopy and SEM EDAX analysis. In the composites spectra the signals correspond to the C=O groups from NVP at 1672-1675 cm-1, and the vibrations of Si-O-C and Si-O-Si groups at 1053-1100 cm-1 from TMVS and NANOSiO2 are visible. Thermal stabilities of the obtained composites were studied by a differential scanning calorimetry DSC. Compared to NVP the samples with TMVS degraded in one stage (422.6-425.3 °C). The NVP-derived materials decomposed in three stages (three endothermic effects on the DSC curves). The addition of NANOSiO2 increases the temperature of composites maximum degradation insignificantly. Additionally, the Shore D hardness test was carried out with original metrological measurements of changes in diameter after indentation in relation to the type of material. The accuracy analysis of the obtained test results was based on a comparative analysis of graphical curves obtained from experimental tests. The values of the changes course of similarity in the examined factors, represented by those of characteristic coefficients were determined based on the Fréchet's theory.

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Influence of Nanoparticles on Thermal and Electrical Conductivity of Composites.

Publications

Influence of Nanoparticles on Thermal and Electrical Conductivity of Composites.

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