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Polypropylene-Based Nanocomposite with Enhanced Aging Stability by Surface Grafting of Silica Nanofillers with a Silane Coupling Agent Containing an Antioxidant.

ABSTRACT: Simultaneous improvement in the mechanical properties and lifetime of polymer nanocomposites is crucially significant to further extend the versatility of polymer materials and reduce environmental impact. In this study, we fabricated reinforced polypropylene (PP)-based nanocomposites with improved aging stability by the addition of surface-modified well-ordered silica nanospheres with a silane coupling agent (SCA) containing hindered phenol antioxidant as a filler. Uniform grafting of the SCA on the filler surface contributed to homogeneous dispersion of the filler into the matrix, leading to improved properties (e.g., stiffness and ductility) and uniform distribution of the antioxidant component into the entire nanocomposite by filler dispersion. The grafting of SCA also likely provides an inhibitory effect on antioxidant migration, which leads to loss of polymer stability during the aging process. This novel idea for the material design of PP-based nanocomposites, which simultaneously enhances their mechanical properties and lifetime, is promising for application in the fabrication of various types of polymer nanocomposites.

SUBMITTER: Watanabe R

PROVIDER: S-EPMC7271349 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Polypropylene-Based Nanocomposite with Enhanced Aging Stability by Surface Grafting of Silica Nanofillers with a Silane Coupling Agent Containing an Antioxidant.

Watanabe Ryota R Sugahara Aki A Hagihara Hideaki H Sakamoto Kei K Nakajima Yumiko Y Naganawa Yuki Y

ACS omega 20200518 21

Simultaneous improvement in the mechanical properties and lifetime of polymer nanocomposites is crucially significant to further extend the versatility of polymer materials and reduce environmental impact. In this study, we fabricated reinforced polypropylene (PP)-based nanocomposites with improved aging stability by the addition of surface-modified well-ordered silica nanospheres with a silane coupling agent (SCA) containing hindered phenol antioxidant as a filler. Uniform grafting of the SCA o ...[more]

PMID: 32548428

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Project description:The current longevity of dental resins intraorally is limited by susceptibility to acidic attacks from bacterial metabolic byproducts and vulnerability to enzymatic or hydrolytic degradation. Here, we demonstrate synthesizing an ionic liquid-based antibiofilm silane effective against Streptococcus mutans, a major caries pathogen. Furthermore, we incorporate this silane into dental resins, creating antibiofilm- and degradation-resistant materials applicable across resin types. FTIR, UV-vis, and NMR spectroscopy confirmed the synthesis of the expected ionic liquid-based silane. The characterization of SiO2 after the silanization indicated the presence of the silane and how it interacted with the oxide. All groups achieved a degree of conversion similar to that found for commercial resin composites immediately and after two months of storage in water. The minimum of 2.5 wt % of silane led to lower softening in solvent than the control group (GCTRL) (p < 0.05). While the flexural strength indicated a lower value from 1 wt % of silane compared to GCTRL (p < 0.05), the ultimate tensile strength did not indicate differences among groups (p > 0.05). There was no difference within groups between the immediate and long-term tests of flexural strength (p > 0.05) or ultimate tensile strength (p > 0.05). The addition of at least 5 wt % of silane reduced the viability of S. mutans compared to GCTRL (p < 0.05). The fluorescence microscopy analysis suggested that the higher the silane concentration, the higher the amount of bacteria with membrane defects. There was no difference among groups in the cytotoxicity test (p > 0.05). Therefore, the developed dental resins displayed biocompatibility, proper degree of conversion, improved resistance against softening in solvent, and stability after 6 months of storage in water. This material could be further developed to produce polymeric antimicrobial layers for different surfaces, supporting various potential avenues in developing novel biomaterials with enhanced therapeutic characteristics using ionic liquid-based materials.

Dataset Information

Polypropylene-Based Nanocomposite with Enhanced Aging Stability by Surface Grafting of Silica Nanofillers with a Silane Coupling Agent Containing an Antioxidant.

Publications

Polypropylene-Based Nanocomposite with Enhanced Aging Stability by Surface Grafting of Silica Nanofillers with a Silane Coupling Agent Containing an Antioxidant.

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