Dataset Information
Crystal structure of {?2-1,2-bis-[(4-methyl-phenyl-sulfan-yl]-3-oxoprop-1-ene-1,3-di-yl-1:2?2 C 3:C 1}dicarbon-yl-1?2 C-[?2-methyl-enebis(di-phenyl-phos-phane)-1:2?2 P:P'](tri-phenyl-phosphane-2?P)iron-platinum(Fe-Pt), [(OC)2Fe(?-dppm){?-C(=O)C(4-MeC6H4SCH2)=CCH2SC6H4Me-4}Pt(PPh3)].
Ontology highlight
ABSTRACT:
SUBMITTER: Mohamed AS
PROVIDER: S-EPMC7336804 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
Publications
Crystal structure of {μ<sub>2</sub>-1,2-bis-[(4-methyl-phenyl-sulfan-yl]-3-oxoprop-1-ene-1,3-di-yl-1:2κ<sup>2</sup> <i>C</i> <sup>3</sup>:<i>C</i> <sup>1</sup>}dicarbon-yl-1κ<sup>2</sup> <i>C</i>-[μ<sub>2</sub>-methyl-enebis(di-phenyl-phos-phane)-1:2κ<sup>2</sup> <i>P</i>:<i>P</i>'](tri-phenyl-phosphane-2κ<i>P</i>)iron-platinum(<i>Fe</i>-<i>Pt</i>), [(OC)<sub>2</sub>Fe(μ-dppm){μ-C(=O)C(4-MeC<sub>6</sub>H<sub>4</sub>SCH<sub>2</sub>)=CCH<sub>2</sub>SC<sub>6</sub>H<sub>4</sub>Me-4}Pt(PPh<sub>3</sub>)].
Acta crystallographica. Section E, Crystallographic communications 20200616 Pt 7
The title compound, [FePt(C<sub>19</sub>H<sub>18</sub>OS<sub>2</sub>)(C<sub>18</sub>H<sub>15</sub>P)(C<sub>25</sub>H<sub>22</sub>P<sub>2</sub>)(CO)<sub>2</sub>], <b>1</b>, [(OC)<sub>2</sub>Fe(μ-dppm)(μ-C(=O)C(CH<sub>2</sub>SC<sub>6</sub>H<sub>4</sub>Me-4)=CCH<sub>2</sub>SC<sub>6</sub>H<sub>4</sub>Me-4)Pt(PPh<sub>3</sub>)], represents the first example of a diphosphane-bridged heterobimetallic Fe-Pt dimetalla-cyclo-pentenone complex resulting from a bimetallic activation of metal-coordinated carb ...[more]