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Tetra-carbonyldi-μ-chlorido-di-chlorido-bis-(η⁵-cyclo-penta-dien-yl)diirondigallium(2 Fe-Ga).

ABSTRACT: The title compound, [Fe₂Ga₂(C₅H₅)₂Cl₄(CO)₄], has an iron-gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol-ecule has an inversion center located between the gallium atoms. The cyclo-penta-dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site.

SUBMITTER: Harakas GN

PROVIDER: S-EPMC9635419 | biostudies-literature | 2022 Aug

REPOSITORIES: biostudies-literature

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Tetra-carbonyldi-μ-chlorido-di-chlorido-bis-(η5-cyclo-penta-dien-yl)diirondigallium(2 Fe-Ga).

Harakas George N GN Demmin Mary Elizabeth ME

IUCrData 20220826 Pt 8

The title compound, [Fe2Ga2(C5H5)2Cl4(CO)4], has an iron-gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol-ecule has an inversion center located between the gallium atoms. The cyclo-penta-dienyl ligand is disordered over two sites with an occupancy of 0.57 (2) for the major occupied site. ...[more]

PMID: 36340981

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