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Crystal structure of La24Ru11.

ABSTRACT: The compound La24Ru11 (tetra-cosa-lanthanum undeca-ruthenium) crystallizes in a Ce24Co11-type structure. The non-centrosymmetric crystal structure (space group P63 mc) contains RuLa6 trigonal prisms, La6 octa-hedra and LaRu4 tetra-hedra and is closely related to that of Ce23Ni7Mg4. This communication highlights the crystal-chemical similarities and points out the differences between the two structures. All of the tested crystals were inversion twins.

SUBMITTER: Cattaneo P 

PROVIDER: S-EPMC7405562 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of La<sub>24</sub>Ru<sub>11</sub>.

Cattaneo P P  

Acta crystallographica. Section E, Crystallographic communications 20200703 Pt 8

The compound La<sub>24</sub>Ru<sub>11</sub> (tetra-cosa-lanthanum undeca-ruthenium) crystallizes in a Ce<sub>24</sub>Co<sub>11</sub>-type structure. The non-centrosymmetric crystal structure (space group <i>P</i>6<sub>3</sub> <i>mc</i>) contains RuLa<sub>6</sub> trigonal prisms, La<sub>6</sub> octa-hedra and LaRu<sub>4</sub> tetra-hedra and is closely related to that of Ce<sub>23</sub>Ni<sub>7</sub>Mg<sub>4</sub>. This communication highlights the crystal-chemical similarities and points out the  ...[more]

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