Ontology highlight
ABSTRACT:
SUBMITTER: Qiu YR
PROVIDER: S-EPMC7480181 | biostudies-literature | 2020 Jun
REPOSITORIES: biostudies-literature
Chemical science 20200527 24
In designing multifunctional materials for potential switches that can be used as memory devices, the high-spin (HS) to low-spin (LS) crossover (SCO) one-dimensional polymer, [Fe<sup>II</sup>(L)(4,4'-bpy)] <sub><i>n</i></sub> , was constructed from a designed redox-active tetrathiafulvalene (TTF) functionalized Schiff-base and the ditopic linker 4,4'-bipyridine (bpy). It exhibits an 8 K hysteretic SCO centred at <i>T</i> <sub>1/2</sub> = 325 K which is coupled to changes in its dielectric consta ...[more]