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Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS.


ABSTRACT: To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography-mass spectrometry (LC-MS) and LC-MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154-272 Da and carbon chain of the length 8-15. The formation of these soluble carbocyclic compounds was proposed to involve hydrolytic ring-opening of the furanic ring, intermolecular aldol condensation, intramolecular aldol condensation, and C-C cleavage reaction. The C-C cleavage reaction was proposed to occur on the dicarbonyl structure of the formed primary polymers.

SUBMITTER: Shi N 

PROVIDER: S-EPMC7496007 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Characterization of the Soluble Products Formed during the Hydrothermal Conversion of Biomass-Derived Furanic Compounds by Using LC-MS/MS.

Shi Ning N   Liu Qiying Q   Liu Ying Y   Chen Lijun L   Zhang Hongyan H   Huang Hongsheng H   Ma Longlong L  

ACS omega 20200901 36


To reveal the hydrothermal conversion routes of the biomass-derived furanic compounds, the soluble products formed during the hydrothermal conversion of 5-hydroxymethylfurfural (HMF), furfural, and furfuryl alcohol were analyzed by liquid chromatography-mass spectrometry (LC-MS) and LC-MS/MS. Multiple carbocyclic compounds containing hydroxy group and carbonyl group were detected, with a molecular mass in the range of 154-272 Da and carbon chain of the length 8-15. The formation of these soluble  ...[more]

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