Ontology highlight
ABSTRACT:
SUBMITTER: Kutahya C
PROVIDER: S-EPMC7496941 | biostudies-literature | 2020 Apr
REPOSITORIES: biostudies-literature
Kütahya Ceren C Meckbach Nicolai N Strehmel Veronika V Gutmann Jochen S JS Strehmel Bernd B
Chemistry (Weinheim an der Bergstrasse, Germany) 20200723 46
NIR exposure at 790 nm activated photopolymerization of monomers comprising UV-absorbing moieties by using [Cu<sup>II</sup> /(TPMA)]Br<sub>2</sub> (TPMA=tris(2-pyridylmethyl)amine) in the ppm range and an alkyl bromide as initiator. Some of them comprised structural elements selected either from those showing proton transfer or photocycloaddition upon UV excitation. Polymers obtained comprise living end groups serving as macroinitiator for controlled synthesis of block copolymers with relatively ...[more]