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Green synthesis of triclinic (anorthic) phase AgCoPO4 nanoparticles: optical studies and theoretical modelling

ABSTRACT: We report the plant-mediated synthesis, structural investigation, optical properties and theoretical modelling of a triclinic (anorthic) phase AgCoPO4 nanoparticles for the first time. As part of green chemistry, the secondary metabolites in the leaf extract of Canna indica were engaged as the reducing/capping agent for the metal nanoparticles. X-ray diffraction (XRD) revealed the presence of an anorthic AgCoPO4 phase, crystallised in a triclinic structure with P -1 space group. Optical studies using UV-vis spectroscopy and photoluminescence are reported. Transmission electron microscopy suggests the formation of quasi-nanocube morphology, unlike the conventional spherically-shaped nanoparticles via plant-mediated reduction method. Elemental composition of the nanohybrid was confirmed by energy-dispersive x-ray spectroscopy (E.D.S.). Evidence of crystallinity was supported by selected area electron diffraction (SAED). Study of the dynamic anisotropy of the nanohybrid at optimised state suggests its proposed application as optical material in colourimetric metal nanoparticles-mediated sensors. Materials chemistry, Nanotechnology, AgCoPO4 phase, Optical properties, Anisotropy, Triclinic, Green chemistry

SUBMITTER: Akinsiku A

PROVIDER: S-EPMC7512005 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Project description:Titanium dioxide (TiO2) nanoparticles were synthesized via a novel eco-friendly green chemistry approach using marine natural extracts of two red algae (Bostrychia tenella and Laurencia obtusa), a green alga (Halimeda tuna), and a brown alga (Sargassum filipendula) along with a marine sponge sample identified as Carteriospongia foliascens. X-ray diffraction (XRD), scanning electron microscope (SEM), UV-Vis, X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and Fourier-transform infrared spectroscopy (FTIR) were employed to characterize the crystal structure, surface morphology, and optical properties of the synthesized nanoparticles. Each of the as-synthesized marine extract based TiO2 nanoparticles was individually incorporated as an antifouling agent to form a newly fabricated marine paint formulation. The newly prepared formulations were applied on unprimed steel panels. A comparative study with a commercial antifouling paint (Sipes Transocean Coatings Optima) was carried out. After 108 days of the coated steel panels' immersion in the Eastern Harbour seawater of Alexandria-Egypt, the prepared paints using B. tenella and C. foliascens extracts demonstrated an excellent antifouling performance toward fouling organisms by inhibiting their settlement and controlling their adhesion onto the immersed panels. In contrast, heavy fouling with barnacles was observed on the surface of the coated panel with the commercial paint. The physicochemical parameters of the seawater surrounding the immersed coated panels were estimated to investigate the influence of the fabricated paint formulations. Interestingly, no effects of the immersed coated panels on the physicochemical characteristics of the surrounding seawater were observed. Based on the obtained results and a comparison with commercially available antifouling products, the marine extract based TiO2 nanoparticle preparations of B. tenella and C. foliascens are promising candidates for eco-friendly antifouling agents. Based on the obtained results and a comparison with commercially available antifouling products, the marine extract based TiO2 nanoparticle preparations of B. tenella and C. foliascens are promising candidates for eco-friendly antifouling agents, which could be attributed to the small crystallite sizes of 22.86 and 8.3 nm, respectively, in addition to the incorporation of carbon in the crystal structure of the nanoparticles.

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Green synthesis of triclinic (anorthic) phase AgCoPO4 nanoparticles: optical studies and theoretical modelling

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