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Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride.

ABSTRACT: Discovering novel materials and improving the properties of existing materials are the main goals in the field of photocatalysis to increase the potential application of the materials. In this paper, a modified graphitic carbon nitride (g-C3N4) photocatalyst named Fe3+-doped alkalized carbon nitride, which couples the photocatalytic reaction with the Fenton reaction, is introduced to demonstrate its Rhodamine B (RhB) degradation and antibacterial properties. Under visible-light irradiation, the degradation rate of RhB was 99.9% after 200 min, while the antibacterial rates of Pseudomonas aeruginosa (P. aeruginosa), Escherichia coli (E. coli), and Staphylococcus aureus (S. aureus) after 300 min were 99.9986%, 99.9974%, and 99.9876%, respectively. Moreover, the repetitive experiments of RhB degradation demonstrate that the proposed photocatalysts have excellent stability and reusability. The active free radical trapping experiments reveal that the superoxide radical (·O2-) is the dominant reactive oxygen species. In addition, the Fenton reaction is introduced into the photocatalytic system due to the doping of Fe3+, and the hydroxyl radical (·OH) produced from the Fenton reaction further enhances the photocatalytic performance. The remarkable improvement in photocatalytic performance of the proposed photocatalyst can be attributed to its broader UV-visible absorption characteristic and the occurrence of the Fenton reaction.

SUBMITTER: Gao Y

PROVIDER: S-EPMC7558592 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride.

Gao Ying Y Duan Jizhou J Zhai Xiaofan X Guan Fang F Wang Xiutong X Zhang Jie J Hou Baorong B

Nanomaterials (Basel, Switzerland) 20200904 9

Discovering novel materials and improving the properties of existing materials are the main goals in the field of photocatalysis to increase the potential application of the materials. In this paper, a modified graphitic carbon nitride (g-C3N4) photocatalyst named Fe3+-doped alkalized carbon nitride, which couples the photocatalytic reaction with the Fenton reaction, is introduced to demonstrate its Rhodamine B (RhB) degradation and antibacterial properties. Unde ...[more]

PMID: 32899800

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Project description:Metal-doped graphitic carbon nitride (MCN) materials have shown great promise as effective photocatalysts for the conversion of acetic acid to carbon dioxide under UV-visible irradiation and are superior to pristine carbon nitride (g-C3N4 , CN). In this study, the effects of metal dopants on the physicochemical properties of metal-doped CN samples (Fe-, Cu-, Zn-, FeCu-, FeZn-, and CuZn-doped CN) and their catalytic activity in the photooxidation of acetic acid were investigated and discussed for their correlation, especially on their surface and bulk structures. The materials in the order of highest to lowest photocatalytic activity are FeZn_CN, FeCu_CN, Fe_CN, and Cu_CN (rates of CO2 evolution higher than for CN), followed by Zn_CN, CuZn_CN, and CN (rates of CO2 evolution lower than CN). Although Fe doping resulted in the extension of the light absorption range, incorporation of metals did not significantly alter the crystalline phase, morphology, and specific surface area of the CN materials. However, the extension of light absorption into the visible region on Fe doping did not provide a suitable explanation for the increase in photocatalytic efficiency. To further understand this issue, the materials were analyzed using two complementary techniques, reversed double-beam photoacoustic spectroscopy (RDB-PAS) and electron spin resonance spectroscopy (ESR). The FeZn_CN, with the highest electron trap density between 2.95 and 3.00 eV, afforded the highest rate of CO2 evolution from acetic acid photodecomposition. All Fe-incorporated CN materials and Cu-CN reported herein can be categorized as high activity catalysts according to the rates of CO2 evolution obtained, higher than 0.15 μmol/min-1, or >1.5 times higher than that of pristine CN. Results from this research are suggestive of a correlation between the rate of CO2 evolution via photocatalytic oxidation of acetic acid with the threshold number of free unpaired electrons in CN-based materials and high electron trap density (between 2.95 and 3.00 eV).

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Photocatalytic Degradation and Antibacterial Properties of Fe3+-Doped Alkalized Carbon Nitride.

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Photocatalytic Degradation and Antibacterial Properties of Fe<sup>3+</sup>-Doped Alkalized Carbon Nitride.

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