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Crystal structure and Hirshfeld surface analysis of di-chlorido-(methanol-?O)bis-(2-methyl-pyridine-?N)copper(II).

ABSTRACT: In the title complex, [CuCl2(C6H7N)2(CH3OH)], the copper atom is five-coordinated by two nitro-gen atoms of 2-methyl-pyridine ligands, two chloro ligands and an oxygen atom of the methanol mol-ecule, being in a tetra-gonal-pyramidal environment with N and Cl atoms forming the basal plane. In the crystal, complex mol-ecules related by the twofold rotation axis are joined into dimeric units by pairs of O-H?Cl hydrogen bonds. These dimeric units are assembled through C-H?Cl inter-actions into layers parallel to (001).

SUBMITTER: Reddy JP

PROVIDER: S-EPMC7643234 | biostudies-literature | 2020 Nov

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of di-chlorido-(methanol-κO)bis-(2-methyl-pyridine-κN)copper(II).

Reddy J Prakasha JP

Acta crystallographica. Section E, Crystallographic communications 20201023 Pt 11

In the title complex, [CuCl2(C6H7N)2(CH3OH)], the copper atom is five-coordinated by two nitro-gen atoms of 2-methyl-pyridine ligands, two chloro ligands and an oxygen atom of the methanol mol-ecule, being in a tetra-gonal-pyramidal environment with N and Cl atoms forming the basal plane. In the crystal, complex mol-ecules related by the twofold rotation axis are joined into dimeric units by pairs of O-H⋯Cl hydrogen bonds. These dimeric unit ...[more]

PMID: 33209351

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