Ontology highlight
ABSTRACT:
SUBMITTER: Bischoff LA
PROVIDER: S-EPMC7689865 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Bischoff Lisa A LA Riefer Jarno J Wirthensohn Raphael R Bischof Tobias T Bertermann Rüdiger R Ignat'ev Nikolai V NV Finze Maik M
Chemistry (Weinheim an der Bergstrasse, Germany) 20200720 60
Salts of the tetrakis(pentafluoroethyl)aluminate anion [Al(C<sub>2</sub> F<sub>5</sub> )<sub>4</sub> ]<sup>-</sup> were obtained from AlCl<sub>3</sub> and LiC<sub>2</sub> F<sub>5</sub> . They were isolated with different counter-cations and characterized by NMR and vibrational spectroscopy and mass spectrometry. Degradation of the [Al(C<sub>2</sub> F<sub>5</sub> )<sub>4</sub> ]<sup>-</sup> ion was found to proceed via 1,2-fluorine shifts and stepwise loss of CF(CF<sub>3</sub> ) under formation o ...[more]