Measurement and Correlation of the Thermal Conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene.

ABSTRACT: New experimental data for the thermal conductivity of cis-1,1,1,4,4,4-hexafluoro-2-butene (R-1336mzz(Z)) are reported for vapor, liquid and supercritical states. These data were obtained with transient hot-wire apparatus over the temperature range from 192 K to 498 K and at pressures from 0.05 MPa to 69 MPa. These data were used to develop a wide-range correlation for the thermal conductivity of the vapor, liquid, and supercritical fluid. The experimental data reported here have an uncertainty of 1 % for the liquid and supercritical regions (densities above 600 kg·m^-3), 1.5 % for vapor and supercritical regions (pressures greater than or equal to 1 MPa and densities less than 200 kg·m^-3), 3 % for supercritical states (densities between 200 kg·m^-3 and 600 kg·m^-3), and 3 % for vapor and supercritical states (pressures below 1 MPa). The thermal-conductivity correlation developed in this work is estimated to have an expanded relative uncertainty, at a 95 % confidence level, ranging from approximately 1.4 % to 4.2 % depending on the temperature and pressure, with larger uncertainties in the critical region.

SUBMITTER: Perkins RA 

PROVIDER: S-EPMC7727279 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature