Dataset Information

Utilization of Jujube Biomass to Prepare Biochar by Pyrolysis and Activation: Characterization, Adsorption Characteristics, and Mechanisms for Nitrogen.

ABSTRACT: The rapid advancement of jujube industry has produced a large amount of jujube biomass waste, requiring the development of new methods for utilization of jujube resources. Herein, medium-temperature pyrolysis is employed to produce carbon materials from jujube waste in an oxygen-free environment. Ten types of jujube biochar (JB) are prepared by modifying different pyrolysis parameters, followed by physical activation. The physicochemical properties of JB are systematically characterized, and the adsorption characteristics of JB for NO₃^- and NH₄⁺ are evaluated via batch adsorption experiments. Furthermore, the pyrolysis and adsorption mechanisms are discussed. The results indicate that the C content, pH, and specific surface area of JB increase with an increase in the pyrolysis temperature from 300 °C to 700 °C, whereas the O and N contents, yield, zeta potential, and total functional groups of JB decrease gradually. The pyrolysis temperature more significantly effects the biochar properties than pyrolysis time. JB affords the highest adsorption capacity for NO₃^- (21.17 mg·g^-1) and NH₄⁺ (30.57 mg·g^-1) at 600 °C in 2 h. The Langmuir and pseudo-second-order models suitably describe the isothermal and kinetic adsorption processes, respectively. The NO₃^- and NH₄⁺ adsorption mechanisms of JB may include surface adsorption, intraparticle diffusion, electrostatic interaction, and ion exchange. In addition, ?-? interaction and surface complexation may also be involved in NH₄⁺ adsorption. The pyrolysis mechanism comprises the combination of hemicellulose, cellulose, and lignin decomposition involving three stages. This study is expected to provide a theoretical and practical basis for the efficient utilization of jujube biomass to develop eco-friendly biochar and nitrogenous wastewater pollution prevention.

SUBMITTER: Zhang D

PROVIDER: S-EPMC7764758 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

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Utilization of Jujube Biomass to Prepare Biochar by Pyrolysis and Activation: Characterization, Adsorption Characteristics, and Mechanisms for Nitrogen.

Zhang Di D Wang Tongtong T Zhi Jinhu J Zheng Qiangqing Q Chen Qiling Q Zhang Cong C Li Yalong Y

Materials (Basel, Switzerland) 20201208 24

The rapid advancement of jujube industry has produced a large amount of jujube biomass waste, requiring the development of new methods for utilization of jujube resources. Herein, medium-temperature pyrolysis is employed to produce carbon materials from jujube waste in an oxygen-free environment. Ten types of jujube biochar (JB) are prepared by modifying different pyrolysis parameters, followed by physical activation. The physicochemical properties of JB are systematically characterized, and the ...[more]

PMID: 33302478

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Project description:Carbonization of biomass can prepare carbon materials with excellent properties. In order to explore the comprehensive utilization and recycling of Caragana korshinskii biomass, 15 kinds of Caragana korshinskii biochar (CB) were prepared by controlling the oxygen-limited pyrolysis process. Moreover, we pay attention to the dynamic changes of microstructure of CB and the by-products. The physicochemical properties of CB were characterized by Scanning Electron Microscope (SEM), BET-specific surface area (BET-SSA), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), and Gas chromatography-mass spectrometry (GC-MS). The optimal preparation technology was evaluated by batch adsorption application experiment of NO3-, and the pyrolysis mechanism was explored. The results showed that the pyrolysis temperature is the most important factor in the properties of CB. With the increase of temperature, the content of C, pH, mesoporous structure, BET-SSA of CB increased, the cation exchange capacity (CEC) decreased and then increased, but the yield and the content of O and N decreased. The CEC, pH, and BET-SSA of CB under each pyrolysis process were 16.64-81.4 cmol·kg-1, 6.65-8.99, and 13.52-133.49 m2·g-1, respectively. CB contains abundant functional groups and mesoporous structure. As the pyrolysis temperature and time increases, the bond valence structure of C 1s, Ca 2p, and O 1s is more stable, and the phase structure of CaCO3 is more obvious, where the aromaticity increases, and the polarity decreases. The CB prepared at 650 °C for 3 h presented the best adsorption performance, and the maximum theoretical adsorption capacity for NO3- reached 120.65 mg·g-1. The Langmuir model and pseudo-second-order model can well describe the isothermal and kinetics adsorption process of NO3-, respectively. Compared with other cellulose and lignin-based biomass materials, CB showed efficient adsorption performance of NO3- without complicated modification condition. The by-products contain bio-soil and tail gas, which are potential source of liquid fuel and chemical raw materials. Especially, the bio-oil of CB contains ?-d-glucopyranose, which can be used in medical tests and medicines.

Dataset Information

Utilization of Jujube Biomass to Prepare Biochar by Pyrolysis and Activation: Characterization, Adsorption Characteristics, and Mechanisms for Nitrogen.

Publications

Utilization of Jujube Biomass to Prepare Biochar by Pyrolysis and Activation: Characterization, Adsorption Characteristics, and Mechanisms for Nitrogen.

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