Ontology highlight
ABSTRACT:
SUBMITTER: Li G
PROVIDER: S-EPMC7782686 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Nature communications 20210104 1
Elegant asymmetric synthesis of hasubanan alkaloids have been developed over the past decades. However, a divergent approach leading to all three sub-classes of this family of natural products remains unknown. We report herein the realization of such an endeavor by accomplishing enantioselective total syntheses of four representative members. The synthesis is characterized by catalytic enantioselective construction of the tricyclic compounds from which three different intramolecular C-N bond for ...[more]