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ABSTRACT:
SUBMITTER: Vershinin V
PROVIDER: S-EPMC7783733 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20201209 1
The selective FeCl<sub>3</sub>-catalyzed oxidative cross-coupling reaction between phenols and primary, secondary, and tertiary 2-aminonaphthalene derivatives was investigated. The generality of this scalable method provides a sustainable alternative for preparing <i>N</i>,<i>O</i>-biaryl compounds that are widely used as ligands and catalysts. Based on a comprehensive kinetic investigation, a catalytic cycle involving a ternary complex that binds to both the coupling partners and the oxidant du ...[more]