Dataset Information
Aerobic Catalyzed Oxidative Cross-Coupling of N,N-Disubstituted Anilines and Aminonaphthalenes with Phenols and Naphthols.
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ABSTRACT:
SUBMITTER: Paniak TJ
PROVIDER: S-EPMC7060808 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Publications
Aerobic Catalyzed Oxidative Cross-Coupling of <i>N</i>,<i>N</i>-Disubstituted Anilines and Aminonaphthalenes with Phenols and Naphthols.
Organic letters 20200212 5
The cross-coupling of <i>N</i>,<i>N</i>-dialkyl aniline and aminonaphthalenes with phenols and naphthols using a Cr-salen catalyst under aerobic conditions was developed. Notably, air serves as an effective oxidant affording products in high selectivity. Initial mechanistic studies suggest an outer-sphere oxidation of the aniline/aminonaphthalene partner, followed by nucleophilic attack of the phenol/naphthol. Single products were observed in most cases, whereas mixtures of C-C and C-O coupled p ...[more]