Unknown

Dataset Information

0

Crystal structure of the coordination polymer catena-poly[[bis-[hy-droxy(phen-yl)acetato-?2 O 1,O 2]zinc(II)]-?2-1,2-bis-(pyridin-4-yl)ethane-?2 N:N'].

ABSTRACT: In the title polymeric ZnII compound, [Zn(C8H7O3)2(C12H12N2)] n , the Zn cation is coordinated by two N atoms from 1,2-bis-(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy-droxy(phen-yl)acetate] anions in a slightly distorted octa-hedral coordination geometry. The 1,2-bis-(pyridin-4-yl)ethane unit bridges two ZnII cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O-H?O and weak C-H ?O hydrogen bonds, with C-H ? ? inter-actions and ?-? inter-actions also being present. The centroid-centroid distance between the phenyl ring of the mandelate group and the 1,2-bis-(pyridine-4-yl)ethane moiety is 4.951?(2)?Å. The 1,2-bis-(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578?(14) for the major component.

SUBMITTER: Fwu Ming S 

PROVIDER: S-EPMC7784659 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Crystal structure of the coordination polymer <i>catena</i>-poly[[bis-[hy-droxy(phen-yl)acetato-κ<sup>2</sup> <i>O</i> <sup>1</sup>,<i>O</i> <sup>2</sup>]zinc(II)]-μ<sub>2</sub>-1,2-bis-(pyridin-4-yl)ethane-κ<sup>2</sup> <i>N</i>:<i>N</i>'].

Fwu Ming Shen S   Shie Fu Lush L  

Acta crystallographica. Section E, Crystallographic communications 20201124 Pt 12

In the title polymeric Zn<sup>II</sup> compound, [Zn(C<sub>8</sub>H<sub>7</sub>O<sub>3</sub>)<sub>2</sub>(C<sub>12</sub>H<sub>12</sub>N<sub>2</sub>)] <sub><i>n</i></sub> , the Zn cation is coordinated by two N atoms from 1,2-bis-(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hy-droxy(phen-yl)acetate] anions in a slightly distorted octa-hedral coordination geometry. The 1,2-bis-(pyridin-4-yl)ethane unit bridges two Zn<sup>II</sup> cations, related by an inversion centre, to for  ...[more]

Similar Datasets

Unknown catena-Poly[[[bis-(methanol-κO)bis-(seleno-cyanato-κN)manganese(II)]-μ-1,2-bis-(pyridin-4-yl)ethane-κ(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane monosolvate].
| S-EPMC3629498 | biostudies-literature
Unknown catena-Poly[[[di-aqua-bis-(seleno-cyanato-κN)iron(II)]-μ-1,2-bis-(pyridin-4-yl)ethane-κ(2) N:N'] 1,2-bis-(pyridin-4-yl)ethane disolvate dihydrate].
| S-EPMC3684883 | biostudies-literature
Unknown catena-Poly[[[(acetato-?O,O')cadmium]-?-acetato-?O,O':O'-?-{1,2-bis-[4-(pyridin-3-yl)pyrimidin-2-ylsulfan-yl]ethane}-?N,N] trihydrate].
| S-EPMC3238649 | biostudies-literature
Unknown catena-Poly[[diaqua-bis-[2-(3-oxo-1,3-di-hydro-2-benzofuran-1-yl)acetato-?O]cobalt(II)]-?-1,2-bis-(pyridin-4-yl)ethane-?(2)N:N'].
| S-EPMC3515166 | biostudies-literature
Unknown catena-Poly[[[bis-(acetato-?(2)O,O')aqua-cadmium]-?-[(pyridin-3-yl)(pyridin-4-yl)methanone]-?(2)N:N'] dihydrate].
| S-EPMC3379068 | biostudies-literature
Unknown catena-Poly[[bis-(acetato-?O)aqua-copper(II)]-?-5-(pyridin-3-yl)pyrimidine-?N:N].
| S-EPMC3254350 | biostudies-literature
Unknown catena-Poly[[diaqua-nickel(II)]-bis-(μ-2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan-yl}acetato)].
| S-EPMC3379099 | biostudies-literature
Unknown Crystal structure of bis-(acetato-κ<sup>2</sup><i>O</i>,<i>O</i>')di-aqua-[1-(pyridin-2-yl-methyl-idene-κ<i>N</i>)-2-(pyridin-2-yl-κ<i>N</i>)hydrazine-κ<i>N</i><sup>1</sup>]terbium(III) nitrate monohydrate.
| S-EPMC5598831 | biostudies-literature
Unknown catena-Poly[[[bis-(methanol-κO)bis-(seleno-cyanato-κN)manganese(II)]-μ-1,2-bis-(pyridin-4-yl)eth-ene-κ(2) N:N'] 1,2-bis-(pyridin-4-yl)eth-ene mono-solvate].
| S-EPMC3684882 | biostudies-literature
Unknown Crystal structure of a looped-chain Co<sup>II</sup> coordination polymer: <i>catena</i>-poly[[bis-(nitrato-κ<i>O</i>)cobalt(II)]bis-[μ-bis-(pyridin-3-ylmeth-yl)sulfane-κ<sup>2</sup><i>N</i>:<i>N</i>']].
| S-EPMC5683494 | biostudies-literature