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An antibonding valence band maximum enables defect-tolerant and stable GeSe photovoltaics.


ABSTRACT: In lead-halide perovskites, antibonding states at the valence band maximum (VBM)-the result of Pb 6s-I 5p coupling-enable defect-tolerant properties; however, questions surrounding stability, and a reliance on lead, remain challenges for perovskite solar cells. Here, we report that binary GeSe has a perovskite-like antibonding VBM arising from Ge 4s-Se 4p coupling; and that it exhibits similarly shallow bulk defects combined with high stability. We find that the deep defect density in bulk GeSe is ~1012?cm-3. We devise therefore a surface passivation strategy, and find that the resulting GeSe solar cells achieve a certified power conversion efficiency of 5.2%, 3.7 times higher than the best previously-reported GeSe photovoltaics. Unencapsulated devices show no efficiency loss after 12 months of storage in ambient conditions; 1100?hours under maximum power point tracking; a total ultraviolet irradiation dosage of 15 kWh m-2; and 60 thermal cycles from -40 to 85?°C.

SUBMITTER: Liu SC 

PROVIDER: S-EPMC7844217 | biostudies-literature | 2021 Jan

REPOSITORIES: biostudies-literature

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An antibonding valence band maximum enables defect-tolerant and stable GeSe photovoltaics.

Liu Shun-Chang SC   Dai Chen-Min CM   Min Yimeng Y   Hou Yi Y   Proppe Andrew H AH   Zhou Ying Y   Chen Chao C   Chen Shiyou S   Tang Jiang J   Xue Ding-Jiang DJ   Sargent Edward H EH   Hu Jin-Song JS  

Nature communications 20210128 1


In lead-halide perovskites, antibonding states at the valence band maximum (VBM)-the result of Pb 6s-I 5p coupling-enable defect-tolerant properties; however, questions surrounding stability, and a reliance on lead, remain challenges for perovskite solar cells. Here, we report that binary GeSe has a perovskite-like antibonding VBM arising from Ge 4s-Se 4p coupling; and that it exhibits similarly shallow bulk defects combined with high stability. We find that the deep defect density in bulk GeSe  ...[more]

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