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N,N'-Bis[2,6-bis-(1-methyl-eth-yl)phen-yl]pyridine-4-carboximidamide toluene hemisolvate.

ABSTRACT: The title compound, C₃₀H₃₉N₃·0.5C₇H₈, is a symmetrically N,N'-disubstituted aryl-amidine containing a 4-pyridyl substituent on the carbon atom of the N-C-N linkage and bulky 2,6-diiso-propyl-phenyl groups on the nitro-gen atoms. It crystallizes in the Z-anti configuration and its amidine C-N bonds present amine [1.368?(1)?Å] and imine [1.286?(1)?Å] features. Intra-molecular hydrogen bonds are present in the structure together with inter-molecular N-H?N and C-H?N inter-actions linking the mol-ecules in chains along the a- and c-axis directions.

SUBMITTER: Cottin L

PROVIDER: S-EPMC7869534 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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N,N'-Bis[2,6-bis-(1-methyl-eth-yl)phen-yl]pyridine-4-carboximidamide toluene hemisolvate.

Cottin Lola L Girard Sarah S Hanan Garry S GS Cibian Mihaela M

Acta crystallographica. Section E, Crystallographic communications 20210112 Pt 2

The title compound, C30H39N3·0.5C7H8, is a symmetrically N,N'-disubstituted aryl-amidine containing a 4-pyridyl substituent on the carbon atom of the N-C-N linkage and bulky 2,6-diiso-propyl-phenyl groups on the nitro-gen atoms. It crystallizes in the Z-anti configuration and its amidine C-N bonds present amine [1.368 (1) Å] and imine [1.286 (1) Å] features. Intra-molecular hydrogen bonds are present in the structure tog ...[more]

PMID: 33614137

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