Ontology highlight
ABSTRACT:
SUBMITTER: Knies M
PROVIDER: S-EPMC7874255 | biostudies-literature | 2021 Feb
REPOSITORIES: biostudies-literature
Knies Maximilian M Groh Matthias F MF Pietsch Tobias T Lê Anh Mai M Ruck Michael M
ChemistryOpen 20201019 2
Bi<sub>2</sub> S<sub>3</sub> was dissolved in the presence of either AuCl/PtCl<sub>2</sub> or AgCl in the ionic liquids [BMIm]Cl ⋅ xAlCl<sub>3</sub> (BMIm=1-n-butyl-3-methylimidazolium; x=4-4.3) through annealing the mixtures at 180 or 200 °C. Upon cooling to room temperature, orange, air-sensitive crystals of [BMIm](Bi<sub>4</sub> S<sub>4</sub> )[AlCl<sub>4</sub> ]<sub>5</sub> (1) or Ag(Bi<sub>7</sub> S<sub>8</sub> )[S(AlCl<sub>3</sub> )<sub>3</sub> ]<sub>2</sub> [AlCl<sub>4</sub> ]<sub>2</sub> ...[more]