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ABSTRACT:
SUBMITTER: Marschner SM
PROVIDER: S-EPMC7898653 | biostudies-literature | 2021 Jan
REPOSITORIES: biostudies-literature
Marschner Stefan M SM Haldar Ritesh R Fuhr Olaf O Wöll Christof C Bräse Stefan S
Chemistry (Weinheim an der Bergstrasse, Germany) 20201210 4
Differently functionalized porphyrin linkers represent the key compounds for the syntheses of new porphyrin-based metal-organic frameworks (MOFs), which have gathered great interest within the last two decades. Herein we report the synthesis of a large range of 5,15-bis(4-ethoxycarbonylphenyl)porphyrin derivatives, through Suzuki and Sonogashira cross-coupling reactions of an easily accessible corresponding meso-dibrominated trans-A<sub>2</sub> B<sub>2</sub> -porphyrin with commercially availabl ...[more]