Dataset Information

Synthesis of an Alginate-Based Fe₃O₄-MnO₂ Xerogel and Its Application for the Concurrent Elimination of Cr(VI) and Cd(II) from Aqueous Solution.

ABSTRACT: In this study, magnetite-manganese oxide (Fe₃O₄-MnO₂) nanoparticles were synthesized and immobilized on alginate, producing a magnetite-manganese oxide xerogel (mMOX). This eco-friendly xerogel was used as an adsorbent of Cr(VI) and Cd(II). It was mesoporous and thermally stable, as determined by Brunauer-Emmett-Teller and thermogravimetric analysis. A scanning electron microscope coupled with an energy-dispersive X-ray system, Zetasizer, and attenuated total reflectance-Fourier transform infrared were used for characterization of adsorbents. The performance of the mMOX was investigated for the simultaneous adsorption of Cr(VI) and Cd(II) at different temperatures, pH values, contact times, initial concentrations of the adsorbate, and adsorbent doses. The developed xerogel (mMOX) showed high adsorption capacities of 3.86 mg/g for Cr(VI) and 3.95 mg/g for Cd(II) on 120 min of contact time with 5 ppm Cr(VI) and Cd(II) solution. The kinetic data fitted well with the pseudo-second order, while the Freundlich isotherm model was found to be fit for adsorption data. Thermodynamic study revealed the adsorption to be spontaneous and exothermic. The adsorbent showed useful application for real water samples by more than 75% uptake of Cr and Cd with low adsorption of Na, K, and Mg. The regeneration study indicated that the mMOX could be reused up to six cycles with more than 50% removal of Cr(VI) and Cd(II) ions from aqueous solution with minimal leaching of metal ions (Fe, Ca, Na, K, and Mn) into the solution.

SUBMITTER: Kumar A

PROVIDER: S-EPMC7906430 | biostudies-literature | 2021 Feb

REPOSITORIES: biostudies-literature

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Publications

Synthesis of an Alginate-Based Fe3O4-MnO2 Xerogel and Its Application for the Concurrent Elimination of Cr(VI) and Cd(II) from Aqueous Solution.

Kumar Aditya A Prasad Satgur S Saxena Prem N PN Ansari Nasreen G NG Patel Devendra K DK

ACS omega 20210129 5

In this study, magnetite-manganese oxide (Fe3O4-MnO2) nanoparticles were synthesized and immobilized on alginate, producing a magnetite-manganese oxide xerogel (mMOX). This eco-friendly xerogel was used as an adsorbent of Cr(VI) and Cd(II). It was mesoporous and thermally stable, as determined by Brunauer-Emmett-Teller and thermogravimetric analysis. A scanning electron microscope coupled with an energy-dispersive X-ray system, Zetasizer, and attenuated total ref ...[more]

PMID: 33644530

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Project description:The efficient removal of toxic metals ions from chemical industry wastewater is considered problematic due to the existence of pollutants as mixtures in the aqueous matrix, thus development of advanced and effective treatment method has been identified as a panacea to the lingering problems of heavy metal pollution. In this study, KIAgNPs decorated MWCNTs nano adsorbent was developed using combination of green chemistry protocol and chemical vapor deposition techniques and subsequently characterized using UV-Vis, HRTEM, HRSEM, XRD, FTIR and XPS. The adsorptive efficiency of MWCNTs-KIAgNPs for the removal of Cr(VI), Ni(II), Fe(II), Cd(II) and physico-chemical parameters like pH, TDS, COD, BOD, nitrates, sulphates, chlorides and phosphates from chemical industrial wastewater was examined in both batch and fixed bed systems. The result exhibited successful deposition of KIAgNPs on the surface of MWCNTs as confirmed by the microstructures, morphology, crystalline nature, functional groups and elemental characteristics of the MWCNTs-KIAgNPs. Optimum batch adsorption parameters include; pH (3 for Cr(VI) and 6 for Ni(II), Fe(II) and Cd(II) ions), contact time (60 min), adsorbent dosage (40 mg) and temperature (318 K). The binding capacities were obtained as follows; Cr6+ (229.540 mg/g), Ni2+ (174.784 mg/g), Fe2+ (149.552) and Cd2+ (121.026 mg/g), respectively. Langmuir isotherm and pseudo-second order kinetic model best described the experimental data in batch adsorption, while the thermodynamic parameters validated the chemisorption and endothermic nature of the adsorption process. In continuous adsorption, the metal ions were effectively removed at low metal influent concentration, low flow rate and high bed depth, whereby the experimental data were designated by Thomas model. The high physico-chemical parameters in the wastewater were successfully treated in both batch and fixed bed systems to fall within WHO permissible concentrations. The adsorption/desorption study illustrated over 80% metal removal by MWCNTs-KIAgNPs even after 8th adsorption cycle. This study demonstrated excellent performance of MWCNTs-KIAgNPs for chemical industry wastewater treatment.

Dataset Information

Synthesis of an Alginate-Based Fe₃O₄-MnO₂ Xerogel and Its Application for the Concurrent Elimination of Cr(VI) and Cd(II) from Aqueous Solution.

Publications

Synthesis of an Alginate-Based Fe<sub>3</sub>O<sub>4</sub>-MnO<sub>2</sub> Xerogel and Its Application for the Concurrent Elimination of Cr(VI) and Cd(II) from Aqueous Solution.

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