Ontology highlight
ABSTRACT:
SUBMITTER: Tanaka K
PROVIDER: S-EPMC8001088 | biostudies-literature | 2021 Mar
REPOSITORIES: biostudies-literature
Molecules (Basel, Switzerland) 20210315 6
π-Electron systems of silicon have attracted attention because of their narrow HOMO-LUMO gap and high reactivity, but the structural diversity remains limited. Herein, new dialkylboryl-substituted disilenes were synthesized by the selective desilylation-borylation of the corresponding trimethylsilyl-substituted disilenes. The dialkylboryl-substituted disilenes were fully characterized by a combination of NMR spectroscopy, MS spectrometry, single-crystal X-ray diffraction analysis, and theoretica ...[more]