True Nature of the Transition-Metal Carbide/Liquid Interface Determines Its Reactivity.

ABSTRACT: Compound materials, such as transition-metal (TM) carbides, are anticipated to be effective electrocatalysts for the carbon dioxide reduction reaction (CO₂RR) to useful chemicals. This expectation is nurtured by density functional theory (DFT) predictions of a break of key adsorption energy scaling relations that limit CO₂RR at parent TMs. Here, we evaluate these prospects for hexagonal Mo₂C in aqueous electrolytes in a multimethod experiment and theory approach. We find that surface oxide formation completely suppresses the CO₂ activation. The oxides are stable down to potentials as low as -1.9 V versus the standard hydrogen electrode, and solely the hydrogen evolution reaction (HER) is found to be active. This generally points to the absolute imperative of recognizing the true interface establishing under operando conditions in computational screening of catalyst materials. When protected from ambient air and used in nonaqueous electrolyte, Mo₂C indeed shows CO₂RR activity.

SUBMITTER: Griesser C 

PROVIDER: S-EPMC8057231 | biostudies-literature | 2021 Apr

REPOSITORIES: biostudies-literature