Unknown

Dataset Information

0

Exceptional Packing Density of Ammonia in a Dual-Functionalized Metal-Organic Framework.


ABSTRACT: We report the reversible adsorption of ammonia (NH3) up to 9.9 mmol g-1 in a robust Al-based metal-organic framework, MFM-303(Al), which is functionalized with free carboxylic acid and hydroxyl groups. The unique pore environment decorated with these acidic sites results in an exceptional packing density of NH3 at 293 K (0.801 g cm-3) comparable to that of solid NH3 at 193 K (0.817 g cm-3). In situ synchrotron X-ray diffraction and inelastic neutron scattering reveal the critical role of free -COOH and -OH groups in immobilizing NH3 molecules. Breakthrough experiments confirm the excellent performance of MFM-303(Al) for the capture of NH3 at low concentrations under both dry and wet conditions.

SUBMITTER: Marsh C 

PROVIDER: S-EPMC8154541 | biostudies-literature |

REPOSITORIES: biostudies-literature

Similar Datasets

| S-EPMC5309720 | biostudies-literature
| S-EPMC6764158 | biostudies-literature
| S-EPMC6813556 | biostudies-literature
| S-EPMC9268624 | biostudies-literature
| S-EPMC8212418 | biostudies-literature
| S-EPMC5496194 | biostudies-literature
| S-EPMC5572147 | biostudies-literature
| S-EPMC10498709 | biostudies-literature
| S-EPMC4972467 | biostudies-literature
| S-EPMC6301759 | biostudies-literature