Ambiphilic Al-Cu Bonding.
Ontology highlight
ABSTRACT:
SUBMITTER: Liu HY
PROVIDER: S-EPMC8252794 | biostudies-literature | 2021 Jun
REPOSITORIES: biostudies-literature
Publications
Ambiphilic Al-Cu Bonding.
Liu Han-Ying HY Schwamm Ryan J RJ Hill Michael S MS Mahon Mary F MF McMullin Claire L CL Rajabi Nasir A NA
Angewandte Chemie (International ed. in English) 20210520 26
Copper-alumanyl complexes, [LCu-Al(SiN<sup>Dipp</sup> )], where L=carbene=NHC<sup>iPr</sup> (N,N'-diisopropyl-4,5-dimethyl-2-ylidene) and <sup>Me2</sup> CAAC (1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) and featuring unsupported Al-Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO<sub>2</sub> implies an ambiphilicity in the Cu-Al interaction that is dependent on the identity of the carbene co-ligand. ...[more]
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