Unknown

Dataset Information

0

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF3+, CF3•, and CF3- Reactivity.

ABSTRACT: Here we report the synthesis and application of trifluoromethyl thianthrenium triflate (TT-CF3+OTf-) as a novel trifluoromethylating reagent, which is conveniently accessible in a single step from thianthrene and triflic anhydride. We demonstrate the use of TT-CF3+OTf- in electrophilic, radical, and nucleophilic trifluoromethylation reactions.

SUBMITTER: Jia H 

PROVIDER: S-EPMC8297735 | biostudies-literature |

REPOSITORIES: biostudies-literature

Json Xml

Similar Datasets

Unknown Improved Synthesis of 2-Trifluoromethyl-10-aminopropylphenothiazine: Making 2-Trifluoromethyl-10-aminopropylphenothiazine Readily Available for Calmodulin Purification.
| S-EPMC6275952 | biostudies-literature
Unknown Utilization of bench-stable and readily available nickel(II) triflate for access to 1,2-cis-2-aminoglycosides.
| S-EPMC5113030 | biostudies-literature
Unknown Trifluoromethyl Vinyl Sulfide: A Building Block for the Synthesis of CF<sub>3</sub>S-Containing Isoxazolidines.
| S-EPMC5822222 | biostudies-literature
Unknown Deoxyfluorination of acyl fluorides to trifluoromethyl compounds by FLUOLEAD<sup>®</sup>/Olah's reagent under solvent-free conditions.
| S-EPMC7753111 | biostudies-literature
Unknown Al(OR<sup>F</sup>)<sub>3</sub> (R<sup>F</sup> = C(CF<sub>3</sub>)<sub>3</sub>) activated silica: a well-defined weakly coordinating surface anion.
| S-EPMC8148071 | biostudies-literature
Unknown Efficient Synthesis of Trifluoromethyl Amines through a Formal Umpolung Strategy from the Bench-Stable Precursor (Me<sub>4</sub> N)SCF<sub>3</sub>.
| S-EPMC6680219 | biostudies-literature
Unknown Theoretical insight into OH- and Cl-initiated oxidation of CF<sub>3</sub>OCH(CF<sub>3</sub>)<sub>2</sub> and CF<sub>3</sub>OCF<sub>2</sub>CF<sub>2</sub>H &fate of CF<sub>3</sub>OC(X•)(CF<sub>3</sub>)<sub>2</sub> and CF<sub>3</sub>OCF<sub>2</sub>CF<sub>2</sub>X• radicals (X=O, O<sub>2</sub>).
| S-EPMC5220334 | biostudies-literature
Unknown Evaluating the electronic structure of formal Ln<sup>II</sup> ions in Ln<sup>II</sup>(C<sub>5</sub>H<sub>4</sub>SiMe<sub>3</sub>)<sub>3</sub><sup>1-</sup> using XANES spectroscopy and DFT calculations.
| S-EPMC5625586 | biostudies-literature
Unknown Malignant hyperthermia when dantrolene is not readily available.
| S-EPMC8051048 | biostudies-literature
Unknown Facile and systematic access to the least-coordinating WCA [(R<sup>F</sup>O)<sub>3</sub>Al-F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> and its more Lewis-basic brother [F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> (R<sup>F</sup> = C(CF<sub>3</sub>)<sub>3</sub>).
| S-EPMC6137444 | biostudies-literature