Ontology highlight
ABSTRACT:
SUBMITTER: Julia F
PROVIDER: S-EPMC8391941 | biostudies-literature | 2021 Aug
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20210810 33
The use of vinyl electrophiles in synthesis has been hampered by the lack of access to a suitable reagent that is practical and of appropriate reactivity. In this work we introduce a vinyl thianthrenium salt as an effective vinylating reagent. The bench-stable, crystalline reagent can be readily prepared from ethylene gas at atmospheric pressure in one step and is broadly useful in the annulation chemistry of (hetero)cycles, N-vinylation of heterocyclic compounds, and palladium-catalyzed cross-c ...[more]