Browse
Submit Data
Databases
API
Help

Dataset Information

26 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Insights into Mechanical, Thermal, and Electrical Properties of Peroxide-Cured Chlorinated Polyethylene/Ethylene Methacrylate Copolymer Blend Vulcanizates.

ABSTRACT: This work unveils the effect of chemical modification of compatible elastomer blends based on the chlorinated polyethylene (CPE) and ethylene methacrylate copolymer (EMA) (60:40 ratio) using dicumyl peroxide (DCP). CPE/EMA blend vulcanizates were prepared by varying the DCP concentration from 0.5 to 3.0 wt %. All blend vulcanizates showed significant enhancement in physiomechanical properties and thermal stability upon increasing the DCP concentration. DCP incorporation also enhanced the compatibility between CPE and EMA rubbers, which was revealed from FTIR data and other technical properties. Specifically, the vulcanizates with 1.5 wt % DCP showed an enormous improvement in mechanical properties and glass transition temperature (T _g) due to various reasons such as cure characteristics, cross-linking densities, co-cross-linking systems, and morphological features. Uniform distribution of DCP in both the elastomeric phases across their interphases caused co-cross-linking, which increased interphase adhesion in the blend vulcanizates. High interphase adhesion of the blend vulcanizates of 1.5 wt % DCP was directly reflected in its improved mechanical, thermal, flame retardation properties and enhanced oil resistance and volume resistivity in comparison to pristine CPE/EMA blend vulcanizates. Also, the volume resistivity and oil resistance properties of blend vulcanizates were found to be marginally improved upon increasing the concentration of DCP.

SUBMITTER: Bhagabati P

PROVIDER: S-EPMC8358960 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Preparation of Polyethylene and Ethylene/Methacrylic Acid Copolymer Blend Films with Tunable Surface Properties through Manipulating Processing Parameters during Film Blowing.

Project description:Polymer films based on polyethylene (PE) and ionomer ethylene/methacrylic acid (EMAA) copolymer blend were prepared by film blowing, whose surface properties were tuned by varying processing parameters, i.e., take up ratio (TUR). Blends of PE/EMAA copolymer were firstly prepared by the melt-mixing method, before being further blown to films. The wettability of the film was investigated by measuring the contact angle/water-film encounter time, and optical properties, i.e., the haze and transmittance. The wettability was found to be enhanced with the increase of TUR. So too was the haze, while the transmittance was found to be almost independent of TUR. The XPS and AFM results directly show the increasing polar functional groups (-COO-) on the surface and roughness with increasing TUR. Further analysis of the 2D SAXS and WAXS unveiled the origin of the invariant transmittance, which resulted from the minor change of the crystallinity and the monotonic increase of the haze, with TUR resulting from the evolution of crystal orientation. In addition to other post-modification methods, the current study provides an alternative route to prepare large-scale PE films as the template for the advanced potential applications, i.e., covering in the layer of roof, the privacy of protective windows, and multitudes of packaging.

| S-EPMC6836035 | biostudies-literature

Antioxidant Activity of New Copolymer Conjugates of Methoxyoligo(Ethylene Glycol)Methacrylate and Betulin Methacrylate with Cerium Oxide Nanoparticles <i>In Vitro</i>.

Project description:The synthesis of two new copolymer conjugates of methoxyoligo(ethylene glycol)methacrylate MPEGMA and betulin methacrylate BM was developed via RAFT polymerization. The molar content of BM units was equal to 9-10 and 13-16 mol%, respectively (HPLC, 1H and 13C NMR); molar weights were equal to 75000-115000. CeO2 NPs as a component of the hybrid material were synthesized for the preparation of the composition with copolymer conjugates of MPEGMA and BM. We showed a significant increase in G6PDH and GR activities by 21-51% and 9-132%, respectively, which was due to the increase in NADPH concentration under the action of copolymers in vitro. The actions of copolymers and CeO2 NPs combination were stronger than those of the individual components: the SOD activity increased by more than 30%, the catalase activity increased dose-dependently from 13 to 45%, and the GR activity increased to 49%. The maximum increase in enzyme activity was observed for the G6PDH from 54% to 151%. The MDA level dose-dependently increased by 3-15% under the action of copolymers compared with the control, and dose-dependently decreased by 3-12% in samples containing CeO2 NPs only. CeO2 NP-copolymer compositions can be used for the design of new biomimetic medical products with controlled antioxidant properties.

| S-EPMC9506406 | biostudies-literature

Asphalt Incorporation with Ethylene Vinyl Acetate (EVA) Copolymer and Natural Rubber (NR) Thermoplastic Vulcanizates (TPVs): Effects of TPV Gel Content on Physical and Rheological Properties.

Project description:Plastic waste has been incorporated with asphalt to improve the physical properties of asphalt and alleviate the increasing trend of plastic waste being introduced into the environment. However, plastic waste comes in different types such as thermoplastic or thermoset, which results in varied properties of polymer modified asphalt (PMA). In this work, four thermoplastic vulcanizates (TPVs) were prepared using different peroxide concentrations to produce four formulations of gel content (with varying extent of crosslinked part) in order to imitate the variation of plastic waste. All four TPVs were then mixed with asphalt at 5 wt% thus producing four formulations of PMA, which went through physical, rheological, and storage stability assessments. PMA with higher gel content possessed lower penetration and higher softening temperature, indicating physically harder appearance of PMA. Superpave parameters remained unchanged among different gel content PMA at temperatures of 64, 70, and 76 °C. PMA with any level of gel content had lower Brookfield viscosity than PMA without gel content at a temperature of 135 °C. Higher gel content resulted in shorter storage stability measured with greater different softening temperatures between top and bottom layers of PMA after 5 days of 163 °C storage. This study shows that asphalt with thermoset plastic waste is harder and easier to pave, thus making the non-recycling thermoset plastic waste more useful and friendly to the environment.

| S-EPMC8123437 | biostudies-literature

Melt-Electrospun Polyethylene Nanofiber Obtained from Polyethylene/Polyvinyl Butyral Blend Film.

Project description:We prepared low-density polyethylene (LDPE) nanofiber, a few hundred nanometers in diameter, using polyvinyl butyral (PVB) and a laser melt-electrospinning (M-ESP) device. We blended PVB with LDPE via an internal melt mixer, removed the PVB after M-ESP by ethanol treatment, and studied the influence of PVB on fiber diameter. A substantial diameter reduction with improved crystallinity of LDPE fiber was observed with increased PVB content in the blend. PVB inclusion also increased the polarity of the LDPE/PVB blend, resulting in better spinnability. The removal of PVB from LDPE/PVB blend fiber caused a massive drop in the LDPE fiber diameter, due to fiber splitting, particularly in PVB-rich samples. Fourier transform infrared (FTIR) spectroscopy of fibers confirmed that the prepared nanofiber was the same as pure LDPE fiber.

| S-EPMC7077628 | biostudies-literature

Characterization of Ultraviolet-Cured Methacrylate Networks: From Photopolymerization to Ultimate Mechanical Properties.

Project description:In this study, the effect of different process conditions on the material properties of a single UV-cured layer of methacrylate resin, typically used in the stereolithography (SLA) process, is assessed. This simplified approach of the SLA process gives the opportunity to study the link between process conditions and mechanical properties without complicated interactions between different layers. Fourier-transform infrared analysis is performed to study the effect of light intensity, curing time, and initiator concentration on the monomer conversion. A model is developed based on the reaction kinetics of photopolymerization that describes and predicts the experimental data. The effect of curing time and light intensity on the glass-transition temperature is studied. A unique relation exists between conversion and glass-transition temperature, independent of the light intensity and curing time. Tensile tests on UV-cured resin show an increase in yield stress with increasing curing time and a linear relation between glass-transition temperature and yield stress. However, a lower light intensity leads to a different network structure characterized by a lower yield stress and glass-transition temperature. The correlations between process conditions and the mechanical properties of UV-cured methacrylate systems are established to better understand the role of the processing parameters involved in the SLA process.

| S-EPMC6906930 | biostudies-literature

Thixotropic Supramolecular Pectin-Poly(Ethylene Glycol) Methacrylate (PEGMA) Hydrogels.

Project description:Pectin is an anionic, water-soluble polymer predominantly consisting of covalently 1,4-linked α-d-galacturonic acid units. This naturally occurring, renewable and biodegradable polymer is underutilized in polymer science due to its insolubility in organic solvents, which renders conventional polymerization methods impractical. To circumvent this problem, cerium-initiated radical polymerization was utilized to graft methoxy-poly(ethylene glycol) methacrylate (mPEGMA) onto pectin in water. The copolymers were characterized by ¹H nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA), and used in the formation of supramolecular hydrogels through the addition of α-cyclodextrin (α-CD) to induce crosslinking. These hydrogels possessed thixotropic properties; shear-thinning to liquid upon agitation but settling into gels at rest. In contrast to most of the other hydrogels produced through the use of poly(ethylene glycol) (PEG)-grafted polymers, the pectin-PEGMA/α-CD hydrogels were unaffected by temperature changes.

| S-EPMC6432130 | biostudies-literature

Thermoresponsive Nanogels of Modified Poly((di(ethylene glycol) methyl ether methacrylate)-co-(2-aminoethyl methacrylate))s.

Project description:A series of copolymers of di(ethylene glycol) methyl ether methacrylate (D) and 2-aminoethyl methacrylate (A) (P(D-co-A)) with variable ratios of comonomers were synthesized using atom transfer radical polymerization. Then, the amino groups of obtained copolymers were modified to clickable azide or prop-2-yn-1-yl carbamate groups. A thermoresponsive copolymers were obtained with the value of cloud point temperature (TCP) dependent on the type and number of functional groups in the copolymer and on the concentration of solutions. For P(D-co-A) copolymers, the TCP increased with increasing content of 2-aminoethyl methacrylate comonomer. The presence of azide and prop-2-yn-1-yl carbamate groups caused the changes of TCP of modified copolymers. All studied copolymers in dilute aqueous solutions aggregated above TCP to nanoparticles with sizes dependent on the solution concentration, heating procedures, and types and numbers of functional groups present in a copolymer chain. The presence of hydrophilic elements in the chain and the increase in the copolymer concentration led to the enlargement of the particle sizes. Aggregates were crosslinked using click reaction between an azide and prop-2-yn-1-yl carbamate groups that led to stable thermoresponsive nanogels. A systematic study of the behavior of copolymers allowed the determination of the chains useful for possible application in drug delivery.

| S-EPMC7463910 | biostudies-literature

Synthesis and Characterization of Syndiotactic Polystyrene-Polyethylene Block Copolymer.

Project description:The direct synthesis of syndiotactic polystyrene-block-polyethylene copolymer (sPS-b-PE) with a diblock structure has been achieved. The synthetic strategy consists of the sequential stereocontrolled polymerization of styrene and ethylene in the presence of a single catalytic system: cyclopentadienyltitanium(IV) trichloride activated by modified methylaluminoxane (CpTiCl3/MMAO). The reaction conditions suitable for affording the partially living polymerization of these monomers were identified, and the resulting copolymer, purified from contaminant homopolymers, was fully characterized. Gel permeation chromatography coupled with two-dimensional NMR spectroscopy COSY, HSQC, and DOSY confirmed the block nature of the obtained polymer, whose thermal behaviour and thin film morphology were also investigated by differential scanning calorimetry, powder wide angle x-ray diffraction, and atomic force microscopy.

| S-EPMC6523272 | biostudies-literature

Onyx (Ethylene-vinyl Alcohol Copolymer) in Peripheral Applications.

Project description:Onyx is a nonadhesive liquid embolic agent approved for the treatment of brain arteriovenous malformations. Here, the use of Onyx is discussed in different peripheral procedures. The Onyx's features, its manipulation, technical details, tips, and tricks are presented followed by illustrative cases.

| S-EPMC3312165 | biostudies-other

Hybrid Copolymerization of Ethylene Oxide and tert-Butyl Methacrylate with Organocatalyst.

Project description:Hybrid copolymerization of structurally different, reactivity and mechanism distinct monomers (e.g., cyclic and vinyl type monomers) is of great interest and challenge for both academic research and practical application. Herein, ethylene oxide-co-tert-butyl methacrylate-co-poly(ethylene glycol) benzyl methacrylate (EO-co-BMA-co-bPEO), a statistical copolymer was synthesized via hybrid copolymerization of EO and BMA using an uncharged, non-nucleophilic organobase t-BuP4 as the catalyst. Detailed characterizations indicate that hybrid copolymerization of ethylene oxide and vinyl monomer forms a statistical copolymer concurrently with the transesterification of tert-butyl group and oligomer PEO anions. The application of the copolymer as all solid lithium-ion battery polymer electrolyte was investigated by detecting the ionic conductivity (σ) with electrical impedance spectrum measurement.

| S-EPMC8347643 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data