Ontology highlight
ABSTRACT:
SUBMITTER: Hao X
PROVIDER: S-EPMC8456975 | biostudies-literature | 2021 Aug
REPOSITORIES: biostudies-literature
Hao Xiaoyu X Li Tian-Ren TR Chen Hao H Gini Andrea A Zhang Xiang X Rosset Stéphane S Mazet Clément C Tiefenbacher Konrad K Matile Stefan S
Chemistry (Weinheim an der Bergstrasse, Germany) 20210708 47
While the integration of supramolecular principles in catalysis attracts increasing attention, a direct comparative assessment of the resulting systems catalysts to work out distinct characteristics is often difficult. Herein is reported how the broad responsiveness of ether cyclizations to diverse inputs promises to fill this gap. Cyclizations in the confined, π-basic and Brønsted acidic interior of supramolecular capsules, for instance, are found to excel with speed (exceeding general Brønsted ...[more]