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Electrical and Structural Properties of Li_1.3Al_0.3Ti_1.7(PO₄)₃-Based Ceramics Prepared with the Addition of Li₄SiO₄.

ABSTRACT: The currently studied materials considered as potential candidates to be solid electrolytes for Li-ion batteries usually suffer from low total ionic conductivity. One of them, the NASICON-type ceramic of the chemical formula Li_1.3Al_0.3Ti_1.7(PO₄)₃, seems to be an appropriate material for the modification of its electrical properties due to its high bulk ionic conductivity of the order of 10^-3 S∙cm^-1. For this purpose, we propose an approach concerning modifying the grain boundary composition towards the higher conducting one. To achieve this goal, Li₄SiO₄ was selected and added to the LATP base matrix to support Li⁺ diffusion between the grains. The properties of the Li_1.3Al_0.3Ti_1.7(PO₄)₃-xLi₄SiO₄ (0.02 ≤ x ≤ 0.1) system were studied by means of high-temperature X-ray diffractometry (HTXRD); ⁶Li, ²⁷Al, ²⁹Si, and ³¹P magic angle spinning nuclear magnetic resonance spectroscopy (MAS NMR); thermogravimetry (TG); scanning electron microscopy (SEM); and impedance spectroscopy (IS) techniques. Referring to the experimental results, the Li₄SiO₄ additive material leads to the improvement of the electrical properties and the value of the total ionic conductivity exceeds 10^-4 S∙cm^-1 in most studied cases. The factors affecting the enhancement of the total ionic conductivity are discussed. The highest value of σ_tot = 1.4 × 10^-4 S∙cm^-1 has been obtained for LATP-0.1LSO material sintered at 1000 °C for 6 h.

SUBMITTER: Kwatek K

PROVIDER: S-EPMC8510155 | biostudies-literature |

REPOSITORIES: biostudies-literature

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