Ontology highlight
ABSTRACT:
SUBMITTER: Wu H
PROVIDER: S-EPMC8662739 | biostudies-literature | 2021 Dec
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20211122 48
Homogeneous and heterogeneous catalyzed reactions can seldom operate synergistically under the same conditions. Here we communicate the use of a single rhodium precursor that acts in both the homogeneous and heterogeneous phases for the asymmetric full saturation of vinylarenes that, to date, constitute an unmet bottleneck in the field. A simple asymmetric hydrogenation of a styrenic olefin, enabled by a ligand accelerated effect, accounted for the facial selectivity in the consecutive arene hyd ...[more]