Novel Heteroleptic Tin(II) Complexes Capable of Forming SnO and SnO₂ Thin Films Depending on Conditions Using Chemical Solution Deposition.

ABSTRACT: A new heteroleptic complex series of tin was synthesized by the salt metathesis reaction of SnX₂ (X = Cl, Br, and I) with aminoalkoxide and various N-alkoxy-functionalized carboxamide ligands. The complexes, [ClSn(dmamp)]₂ (1), [BrSn(dmamp)]₂ (2), and [ISn(dmamp)]₂ (3), were prepared from the salt metathesis reaction of SnX₂ with one equivalent of dmamp; [Sn(dmamp)(empa)]₂ (4), [Sn(dmamp)(mdpa)]₂ (5), and [Sn(dmamp)(edpa)]₂ (6) were prepared via the salt metathesis reaction using complex 2 with one equivalent of N-alkoxy-functionalized carboxamide ligand. Complexes 1-5 displayed dimeric molecular structures with tin metal centers interconnected by μ₂-O bonding via the alkoxy oxygen atom. The molecular structures of complexes 1-5 showed distorted trigonal bipyramidal geometries with lone pair electrons in the equatorial position. Using complex 6 as a tin precursor, SnO _x films were deposited by chemical solution deposition (CSD) and subsequent post-deposition annealing (PDA) at high temperatures. SnO and SnO₂ films were selectively obtained under controlled PDA atmospheres of argon and oxygen, respectively. The SnO films featured a tetragonal romarchite structure with high crystallinity and a preferred growth orientation along the (101) plane. They also exhibited a lower transmittance of >52% at 400 nm due to an optical band gap of 2.9 eV. In contrast, the SnO₂ films exhibited a tetragonal cassiterite crystal structure and an extremely high transmittance of >97% at 400 nm was observed with an optical band gap of 3.6 eV.

SUBMITTER: Han SH 

PROVIDER: S-EPMC8757355 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature