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Thermal Degradation Kinetics Analysis of Ethylene-Propylene Copolymer and EP-1-Hexene Terpolymer.

ABSTRACT: LLDPE is a less crystalline polymer with vast industrial and domestic applications. It is imperative to understand the synthesis, processing conditions, and thermal degradation mechanism of the co- as well as terpolymers. This paper reports the in-situ synthesis and thermal degradation studies of the ethylene-propylene copolymer and ethylene-propylene-1-hexene terpolymer and its nanocomposite with ZnAL LDH sheets. The 1-hexene dosing during the in-situ process influenced the product yield and immensely affected the thermal stability of the resultant polymer. One milliliter 1-hexene in-situ addition increased the product yield by 170 percent, while the temperature at 10 percent weight loss in TGA was dropped by about 60 °C. While only 0.3 weight percent ZnAL LDH addition in the terpolymer improved the thermal stability by 10 °C. A master plot technique and combined kinetics analysis (CKA) were deployed to access the thermal degradation mechanism of the synthesized polymers.

SUBMITTER: Mazhar H

PROVIDER: S-EPMC8839618 | biostudies-literature | 2022 Feb

REPOSITORIES: biostudies-literature

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Thermal Degradation Kinetics Analysis of Ethylene-Propylene Copolymer and EP-1-Hexene Terpolymer.

Mazhar Hassam H Shehzad Farrukh F Hong Sung-Gil SG Al-Harthi Mamdouh A MA

Polymers 20220207 3

LLDPE is a less crystalline polymer with vast industrial and domestic applications. It is imperative to understand the synthesis, processing conditions, and thermal degradation mechanism of the co- as well as terpolymers. This paper reports the in-situ synthesis and thermal degradation studies of the ethylene-propylene copolymer and ethylene-propylene-1-hexene terpolymer and its nanocomposite with ZnAL LDH sheets. The 1-hexene dosing during the in-situ process influenced the product yield and im ...[more]

PMID: 35160623

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Project description:The kinetics of ethylene and propylene polymerization catalyzed by homogeneous metallocene were investigated using 2-thiophenecarbonyl chloride followed by quenched-flow methods. The studied metallocene catalysts are: rac-Me2Si(2-Me-4-Ph-Ind)2ZrCl2 (Mt-I), rac-Et(Ind)2ZrCl2 (Mt-II) activated with ([Me2NPh][B(C6F5)4] (Borate-I), [Ph3C][B(C6F5)4] (Borate-II), and were co-catalyzed with different molar ratios of alkylaluminum such as triethylaluminium (TEA) and triisobutylaluminium (TIBA). The change in molecular weight, molecular weight distribution, microstructure and thermal properties of the synthesized polymer are discussed in detail. Interestingly, both Mt-I and Mt-II showed high activity in polyethylene with productivities between 3.17 × 106 g/molMt·h to 5.06 × 106 g/molMt·h, activities were very close to each other with 100% TIBA, but Mt-II/borate-II became more active when TEA was more than 50% in cocatalyst. Similarly, Polypropylene showed the highest activity of 11.07 106 g /molMt·h with Mt-I/Borate-I/TIBA. The effects of alkylaluminum on PE molecular weight were much more complicated; MWD curve changed from mono-modal in Mt-I/borate-I/TIBA to bimodal type when TIBA was replaced by different amounts of TEA. In PE, the active center fractions [C*]/[Zr] of Mt-I/borate were higher than that of Mt-II/borate and average chain propagation rate constant (kp) value slightly decreased with the increase of TEA/TIBA ratio, but the Mt-II/borate systems showed higher kp 1007 kp (L/mol·s). In PP, the Mt-I/borate presented much higher [C*]/[Zr] and kp value than the Mt-II. This work also extend to investigate the mechanistic features of zirconocenes catalyzed olefin polymerizations that addressed the largely unknown issues in zirconocenes in the distribution of the catalyst, between species involved in polymer chain growth and dormant state. In both metallocene systems, chain transfer with alkylaluminum is the dominant way of chain termination. To understand the mechanism of cocatalyst effects on PE Mw and (MWD), the unsaturated chain ends formed via ?-H transfer have been investigated by 1H NMR analysis.

Dataset Information

Thermal Degradation Kinetics Analysis of Ethylene-Propylene Copolymer and EP-1-Hexene Terpolymer.

Publications

Thermal Degradation Kinetics Analysis of Ethylene-Propylene Copolymer and EP-1-Hexene Terpolymer.

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