Stoichiometry design in hierarchical CoNiFe phosphide for highly efficient water oxidation.

ABSTRACT: Rational composition design of trimetallic phosphide catalysts is of significant importance for enhanced surface reaction and efficient catalytic performance. Herein, hierarchical Co _x Ni _y Fe _z P with precise control of stoichiometric metallic elements (x:y:z = (1-10):(1-10):1) has been synthesized, and Co_1.3Ni_0.5Fe_0.2P, as the most optimal composition, exhibits remarkable catalytic activity (η = 320 mV at 10 mA cm^-2) and long-term stability (ignorable decrease after 10 h continuous test at the current density of 10 mA cm^-2) toward oxygen evolution reaction (OER). It is found that the surface P in Co_1.3Ni_0.5Fe_0.2P was replaced by O under the OER process. The density function theory calculations before and after long-term stability tests suggest the clear increasing of the density of states near the Fermi level of Co_1.3Ni_0.5Fe_0.2P/Co_1.3Ni_0.5Fe_0.2O, which could enhance the OH^- adsorption of our electrocatalysts and the corresponding OER performance.

Electronic supplementary material

Supplementary material is available in the online version of this article at 10.1007/s40843-022-2061-x.

SUBMITTER: Chen J 

PROVIDER: S-EPMC9136762 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature