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An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons.

ABSTRACT: Two-dimensional fused aromatic networks (2D FANs) have emerged as a highly versatile alternative to holey graphene. The synthesis of 2D FANs with increasingly larger lattice dimensions will enable new application perspectives. However, the synthesis of larger analogues is mostly limited by lack of appropriate monomers and methods. Herein, we describe the synthesis, characterisation and properties of an expanded 2D FAN with 90-ring hexagons, which exceed the largest 2D FAN lattices reported to date.

SUBMITTER: Riano A

PROVIDER: S-EPMC9300145 | biostudies-literature | 2022 Jan

REPOSITORIES: biostudies-literature

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An Expanded 2D Fused Aromatic Network with 90-Ring Hexagons.

Riaño Alberto A Strutyński Karol K Liu Meng M Stoppiello Craig T CT Lerma-Berlanga Belén B Saeki Akinori A Martí-Gastaldo Carlos C Khlobystov Andrei N AN Valenti Giovanni G Paolucci Francesco F Melle-Franco Manuel M Mateo-Alonso Aurelio A

Angewandte Chemie (International ed. in English) 20211202 2

Two-dimensional fused aromatic networks (2D FANs) have emerged as a highly versatile alternative to holey graphene. The synthesis of 2D FANs with increasingly larger lattice dimensions will enable new application perspectives. However, the synthesis of larger analogues is mostly limited by lack of appropriate monomers and methods. Herein, we describe the synthesis, characterisation and properties of an expanded 2D FAN with 90-ring hexagons, which exceed the largest 2D FAN lattices reported to da ...[more]

PMID: 34748268

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