Browse
Submit Data
Databases
API
Help

Dataset Information

16 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Boosting Hydrogen Evolution at Visible Light Wavelengths by Using a Photocathode with Modal Strong Coupling between Plasmons and a Fabry-Perot Nanocavity.

ABSTRACT: Hot-hole injection from plasmonic metal nanoparticles to the valence band of p-type semiconductors and reduction by hot electrons should be improved for efficient and tuneable reduction to obtain beneficial chemical compounds. We employed the concept of modal strong coupling between plasmons and a Fabry-Pérot (FP) nanocavity to enhance the hot-hole injection efficiency. We fabricated a photocathode composed of gold nanoparticles (Au-NPs), p-type nickel oxide (NiO), and a platinum film (Pt film) (ANP). The ANP structure absorbs visible light over a broad wavelength range from 500 nm to 850 nm via hybrid modes based on the modal strong coupling between the plasmons of Au-NPs and the FP nanocavity of NiO on a Pt film. All wavelength regions of the hybrid modes of the modal strong coupling system promoted hot-hole injection from the Au-NPs to NiO and proton/water reduction by hot electrons. The incident photon-to-current efficiency based on H₂ evolution through water/proton reduction by hot electrons reached 0.2 % at 650 nm and 0.04 % at 800 nm.

SUBMITTER: Oshikiri T

PROVIDER: S-EPMC9311645 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

A Perfect Absorber Based on Similar Fabry-Perot Four-Band in the Visible Range.

Project description:A simple metamaterial absorber is proposed to achieve near-perfect absorption in visible and near-infrared wavelengths. The absorber is composed of metal-dielectric-metal (MIM) three-layer structure. The materials of these three-layer structures are Au, SiO2, and Au. The top metal structure of the absorber is composed of hollow three-dimensional metal rings regularly arranged periodically. The results show that the high absorption efficiency at a specific wavelength is mainly due to the resonance of the Fabry-Perot effect (FP) in the intermediate layer of the dielectric medium, resulting in the resonance light being trapped in the middle layer, thus improving the absorption efficiency. The almost perfect multiband absorption, which is independent of polarization angle and insensitivity of incident angle, lends the absorber great application prospects for filtering and optoelectronics.

| S-EPMC7153252 | biostudies-literature

Water Oxidation under Modal Ultrastrong Coupling Conditions Using Gold/Silver Alloy Nanoparticles and Fabry-Perot Nanocavities.

Project description:We developed a photoanode consisting of Au-Ag alloy nanoparticles (NPs), a TiO2 thin film and a Au film (AATA) under modal strong coupling conditions with a large splitting energy of 520 meV, which can be categorized into the ultrastrong coupling regime. We fabricated a photoanode under ultrastrong coupling conditions to verify the relationship between the coupling strength and photoelectric conversion efficiency and successfully performed efficient photochemical reactions. The AATA photoanode showed a 4.0 % maximum incident photon-to-current efficiency (IPCE), obtained at 580 nm, and the internal quantum efficiency (IQE) was 4.1 %. These results were attributed to the high hot-electron injection efficiency due to the larger near-field enhancement and relatively negative potential distribution of the hot electrons. Furthermore, hybrid mode-induced water oxidation using AATA structures was performed, with a Faraday efficiency of more than 70 % for O2 evolution.

| S-EPMC8456937 | biostudies-literature

Transformation optics with Fabry-Perot resonances.

Project description:Transformation optics is a powerful tool to design various novel devices, such as invisibility cloak. Fantastic effects from this technique are usually accompanied with singular mappings, resulting in challenging implementations and narrow bands of working frequencies. Here in this article, Fabry-Pérot resonances in materials of extreme anisotropy are used to design various transformation optical devices that are not only easy to realize but also work well for a set of resonant frequencies (multiple frequencies). As an example, a prototype of a cylindrical concentrator is fabricated for microwaves.

| S-EPMC4345524 | biostudies-literature

Strong coupling of diffraction coupled plasmons and optical waveguide modes in gold stripe-dielectric nanostructures at telecom wavelengths.

Project description:We propose a hybrid plasmonic device consisting of a planar dielectric waveguide covering a gold nanostripe array fabricated on a gold film and investigate its guiding properties at telecom wavelengths. The fundamental modes of a hybrid device and their dependence on the key geometric parameters are studied. A communication length of 250 μm was achieved for both the TM and TE guided modes at telecom wavelengths. Due to the difference between the TM and TE light propagation associated with the diffractive plasmon excitation, our waveguides provide polarization separation. Our results suggest a practical way of fabricating metal-nanostripes-dielectric waveguides that can be used as essential elements in optoelectronic circuits.

| S-EPMC5364552 | biostudies-literature

Chirality Enhancement Using Fabry-Perot-Like Cavity.

Project description:Chiral molecules that do not superimpose on their mirror images are the foundation of all life forms on earth. Chiral molecules exhibit chiroptical responses, i.e., they have different electromagnetic responses to light of different circular polarizations. However, chiroptical responses in natural materials, such as circular dichroism and optical rotation dispersion, are intrinsically small because the size of a chiral molecule is significantly shorter than the wavelength of electromagnetic wave. Conventional technology for enhancing chiroptical signal entails demanding requirements on precise alignment of the chiral molecules to certain nanostructures, which however only leads to a limited performance. Herein, we show a new approach towards enhancement of chiroptical effects through a Fabry-Pérot (FP) cavity formed by two handedness-preserving metamirrors operating in the GHz region. We experimentally show that the FP cavity resonator can enhance the optical activity of the chiral molecule by an order of magnitude. Our approach may pave the way towards state-of-the-art chiral sensing applications.

| S-EPMC7064819 | biostudies-literature

Theory for Perfect Transmodal Fabry-Perot Interferometer.

Project description:We establish the theory for perfect transmodal Fabry-Perot interferometers that can convert longitudinal modes solely to transverse modes and vice versa, reaching up to 100% efficiency. Two exact conditions are derived for plane mechanical waves: simultaneous constructive interferences of each of two coupled orthogonal modes, and intermodal interference at the entrance and exit sides of the interferometer with specific skew polarizations. Because the multimodal interferences and specific skew motions require unique anisotropic interferometers, they are realized by metamaterials. The observed peak patterns by the transmodal interferometers are similar to those found in the single-mode Fabry-Perot resonance, but multimodality complicates the involved mechanics. We provide their design principle and experimented with a fabricated interferometer. This theory expands the classical Fabry-Perot resonance to the realm of mode-coupled waves, having profound impact on general wave manipulation. The transmodal interferometer could sever as a device to transfer wave energy freely between dissimilar modes.

| S-EPMC5758750 | biostudies-literature

A tunable Fabry-Perot quantum Hall interferometer in graphene.

Project description:Electron interferometry with quantum Hall (QH) edge channels in semiconductor heterostructures can probe and harness the exchange statistics of anyonic excitations. However, the charging effects present in semiconductors often obscure the Aharonov-Bohm interference in QH interferometers and make advanced charge-screening strategies necessary. Here we show that high-mobility monolayer graphene constitutes an alternative material system, not affected by charging effects, for performing Fabry-Pérot QH interferometry in the integer QH regime. In devices equipped with gate-tunable quantum point contacts acting on the edge channels of the zeroth Landau level, we observe-in agreement with theory-high-visibility Aharonov-Bohm interference widely tunable through electrostatic gating or magnetic fields. A coherence length of 10 μm at a temperature of 0.02 K allows us to further achieve coherently coupled double Fabry-Pérot interferometry. In future, QH interferometry with graphene devices may enable investigations of anyonic excitations in fractional QH states.

| S-EPMC7610789 | biostudies-literature

Adaptive optics enhanced sensitivity in Fabry-Perot based photoacoustic tomography.

Project description:All-optical ultrasound detection bears a number of unique advantages for photoacoustic tomography, including the ability for high resolution sampling of the acoustic field and its compatibility with a wide variety of other optical modalities. However, optical schemes based on miniaturized cavities are sensitive to optical aberrations as well as manufacturing-induced cavity imperfections which degrade sensor sensitivity and deteriorate photoacoustic image quality. Here we present an experimental method based on adaptive optics that is capable of enhancing the overall sensitivity of Fabry-Pérot based photoacoustic sensors. We experimentally observe clear improvements in photoacoustic signal detection as well as overall image quality after photoacoustic tomography reconstructions when applied to mammalian tissues in vivo.

| S-EPMC8173089 | biostudies-literature

Versatile tissue lasers based on high-Q Fabry-Perot microcavities.

Project description:Biolasers are an emerging technology for next generation biochemical detection and clinical applications. Progress has recently been made to achieve lasing from biomolecules and single living cells. Tissues, which consist of cells embedded in an extracellular matrix, mimic more closely the actual complex biological environment in a living body and therefore are of more practical significance. Here, we developed a highly versatile tissue laser platform, in which tissues stained with fluorophores are sandwiched in a high-Q Fabry-Pérot microcavity. Distinct lasing emissions from muscle and adipose tissues stained respectively with fluorescein isothiocyanate (FITC) and boron-dipyrromethene (BODIPY), and hybrid muscle/adipose tissue with dual staining were achieved with a threshold of only ∼10 μJ mm-2. Additionally, we investigated how the tissue structure/geometry, tissue thickness, and staining dye concentration affect the tissue laser. Lasing emission from FITC conjugates (FITC-phalloidin) that specifically target F-actin in muscle tissues was also realized. It is further found that, despite the large fluorescence spectral overlap between FITC and BODIPY in tissues, their lasing emissions could be clearly distinguished and controlled due to their narrow lasing bands and different lasing thresholds, thus enabling highly multiplexed detection. Our tissue laser platform can be broadly applicable to various types of tissues/diseases. It provides a new tool for a wide range of biological and biomedical applications, such as diagnostics/screening of tissues and identification/monitoring of biological transformations in tissue engineering.

| S-EPMC5289748 | biostudies-literature

Direct laser-written optomechanical membranes in fiber Fabry-Perot cavities.

Project description:Integrated micro- and nanophotonic optomechanical experiments enable the manipulation of mechanical resonators on the single phonon level. Interfacing these structures requires elaborate techniques limited in tunability, flexibility, and scaling towards multi-mode systems. Here, we demonstrate a cavity optomechanical experiment using 3D-laser-written polymer membranes inside fiber Fabry-Perot cavities. Vacuum coupling rates of g0/2π ≈ 30 kHz to the fundamental megahertz mechanical mode are reached. We observe optomechanical spring tuning of the mechanical resonator frequency by tens of kilohertz exceeding its linewidth at cryogenic temperatures. The direct fiber coupling, its scaling capabilities to coupled resonator systems, and the potential implementation of dissipation dilution structures and integration of electrodes make it a promising platform for fiber-tip integrated accelerometers, optomechanically tunable multi-mode mechanical systems, and directly fiber-coupled systems for microwave to optics conversion.

| S-EPMC10764917 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data